Surface Science
Foundations of Catalysis and Nanoscience
(Sprache: Englisch)
Das Werk bietet auch ins einer Neuauflage einen umfassenden Überblick zum aktuellen Forschungstand dieses für die industrielle Anwendung so zentralen Gebietes der Chemie. Zwei neu eingefügte Kapitel geben vertiefende Einblicke in unterschiedliche Aspekte der Nanowissenschaften.
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Produktinformationen zu „Surface Science “
Das Werk bietet auch ins einer Neuauflage einen umfassenden Überblick zum aktuellen Forschungstand dieses für die industrielle Anwendung so zentralen Gebietes der Chemie. Zwei neu eingefügte Kapitel geben vertiefende Einblicke in unterschiedliche Aspekte der Nanowissenschaften.
Klappentext zu „Surface Science “
Surface science has evolved from being a sub-field of chemistry or physics, and has now established itself as an interdisciplinary topic. Knowledge has developed sufficiently that we can now understand catalysis from a surface science perspective. No-where is the underpinning nature of surface science better illustrated than with nanoscience.Now in its third edition, this successful textbook aims to provide students with an understanding of chemical transformations and the formation of structures at surfaces. The chapters build from simple to more advanced principles with each featuring exercises, which act not only to demonstrate concepts arising in the text but also to form an integral part of the book, with the last eight chapters featuring worked solutions.
This completely revised and expanded edition features:
More than 100 new pages of extensive worked solutions
New topics, including: Second harmonic generation (SHG), Sum Frequency Generation (SFG) at interfaces and capillary waves
An expanded treatment of charge transfer and carbon-based materials including graphene
Extended 'Frontiers and Challenges' sections at the end of each chapter.
This text is suitable for all students taking courses in surface science in Departments of Chemistry, Physics, Chemical Engineering and Materials Science, as well as for researchers and professionals requiring an up-to-date review of the subject.
Inhaltsverzeichnis zu „Surface Science “
Acknowledgements xv1 Introduction 1I.1 Heterogeneous catalysis 2I.2 Why surfaces? 3I.3 Where are heterogeneous reactions important? 3I.4 Semiconductor processing and nanotechnology 4I.5 Other areas of relevance 5I.6 Structure of the book 51 Bulk and Surface Structure 91.1 Clean surface structure 101.2 Reconstruction and adsorbate structure 221.3 Band structure of solids 301.4 The vibrations of solids 411.5 Summary of important concepts 431.6 Frontiers and challenges 441.7 Further reading 441.8 Exercises 442 Experimental Probes and Techniques 512.1 Ultrahigh vacuum 512.2 Light and electron sources 532.3 Molecular beams 572.4 Scanning probe techniques 632.5 Low energy electron diffraction (LEED) 732.6 Electron spectroscopy 802.7 Vibrational spectroscopy 952.8 Second harmonic and sum frequency generation 1032.9 Other surface analytical techniques 1052.10 Summary of important concepts 1062.11 Frontiers and challenges 1062.12 Further reading 1072.13 Exercises 1073 Chemisorption, Physisorption and Dynamics 1153.1 Types of interactions 1153.2 Binding sites and diffusion 1163.3 Physisorption 1203.4 Non-dissociative chemisorption 1213.5 Dissociative chemisorption: H2 on a simple metal 1293.6 What determines the reactivity of metals? 1303.7 Atoms and molecules incident on a surface 1333.8 Microscopic reversibility in Ad/Desorption phenomena 1443.9 The influence of individual degrees of freedom on adsorption and desorption 1483.10 Translations, corrugation, surface atom motions 1503.11 Rotations and adsorption 1563.12 Vibrations and adsorption 1583.13 Competitive adsorption and collision induced processes 1583.14 Classification of reaction mechanisms 1613.15 Measurement of sticking coefficients 1653.16 Summary of important concepts 1683.17 Frontiers and challenges 1693.18 Further reading 1703.19 Exercises 1704 Thermodynamics and Kinetics of Adsorption and Desorption 1854.1 Thermodynamics of Ad/Desorption 1854.2 Adsorption isotherms from thermodynamics 1904.3 Lateral
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interactions 1934.4 Rate of desorption 1944.5 Kinetics of adsorption 2024.6 Adsorption isotherms from kinetics 2104.7 Temperature programmed desorption (TPD) 2134.8 Summary of important concepts 2214.9 Frontiers and challenges 2224.10 Further reading 2224.11 Exercises 2225 Liquid Interfaces 2295.1 Structure of the liquid/solid interface 2295.2 Surface energy and surface tension 2345.3 Liquid films 2395.4 Langmuir films 2415.5 Langmuir-Blodgett films 2435.6 Self assembled monolayers (SAMs) 2485.7 Thermodynamics of liquid interfaces 2545.8 Electrified and charged interfaces 2575.9 Summary of important concepts 2615.10 Frontiers and challenges 2625.11 Further reading 2625.12 Exercises 2636 Heterogeneous Catalysis 2676.1 The prominence of heterogeneous reactions 2676.2 Measurement of surface kinetics and reaction mechanisms 2696.3 Haber-Bosch process 2736.4 From microscopic kinetics to catalysis 2776.5 Fischer-Tropsch synthesis and related chemistry 2836.6 The three-way automotive catalyst 2866.7 Promoters 2886.8 Poisons 2906.9 Bimetallic and bifunctional catalysts 2916.10 Rate oscillations and spatiotemporal pattern formation 2926.11 Sabatier analysis and optimal catalyst selection 2956.12 Summary of important concepts 2966.13 Frontiers and challenges 2976.14 Further reading 2986.15 Exercises 2987 Growth and Epitaxy 3057.1 Stress and strain 3057.2 Types of interfaces 3087.3 Surface energy, surface tension and strain energy 3107.4 Growth modes 3117.5 Nucleation theory 3177.6 Growth away from equilibrium 3197.7 Techniques for growing layers 3227.8 Catalytic growth of nanotubes and nanowires 3277.9 Etching 3327.10 Summary of important concepts 3447.11 Frontiers and challenges 3447.12 Further reading 3457.13 Exercises 3458 Laser and Non-Thermal Chemistry: Photon and Electron Stimulated Chemistry and Atom Manipulation 3538.1 Photon excitation of surfaces 3548.2 Mechanisms of electron and photon stimulated processes 3668.3 Photon and electron induced chemistry at surfaces 3748.4 Charge transfer and electrochemistry 3848.5 Tip Induced process: mechanisms of atom manipulation 3978.6 Summary of important concepts 4048.7 Frontiers and challenges 4048.8 Further reading 4058.9 Exercises 405References 4089 Answers to Exercises from Chapter 1. Bulk and Surface Structure 41510 Answers to Exercises from Chapter 2. Experimental Probes and Techniques 42711 Answers to Exercises from Chapter 3. Chemisorption, Physisorption and Dynamics 44512 Answers to Exercises from Chapter 4. Thermodynamics and Kinetics of Adsorption and Desorption 46513 Answers to Exercises from Chapter 5. Liquid Interfaces 48714 Answers to Exercises from Chapter 6. Heterogeneous Catalysis 49915 Answers to Exercises From Chapter 7. Growth and Epitaxy 50916 Answers to exercises from Chapter 8. Laser and Nonthermal Chemistry 515Appendix I Abbreviations and Prefixes 531Appendix II Symbols 535Appendix III Useful Mathematical Expressions 541Index 545
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Bibliographische Angaben
- Autor: Kurt W. Kolasinski
- 2012, 3. Aufl., 572 Seiten, mit zahlreichen Abbildungen, Maße: 19,2 x 25,1 cm, Kartoniert (TB), Englisch
- Verlag: Wiley & Sons
- ISBN-10: 1119990351
- ISBN-13: 9781119990352
- Erscheinungsdatum: 23.04.2012
Sprache:
Englisch
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