Functional Polymers by Post-Polymerization Modification

HISTORY OF POST-POLYMERIZATION MODIFICATIONIntroduction Post-polymerization Modification via Thiol-ene Addition Post-polymerization Modification of Epoxides, Anhydrides, Oxazolines, and Isocyanates Post-polymerization Modification of Active Esters Post-polymerization Modification via Thiol-Disulfide Exchange Post-polymerization Modification via Diels-Alder Reactions Post-polymerization Modification via Michael-Type AdditionPost-polymerization Modification via Azide Alkyne Cycloaddition Reactions Post-polymerization Modification of Ketones and Aldehydes Post-polymerization Modifications via Other Highly Efficient Reactions Concluding Remarks POST-POLYMERIZATION MODIFICATIONS VIA ACTIVE ESTERS Introduction Active Esters in the Side Group Star PolymersActive Esters at the End GroupsControlled Positioning of Active Ester MoietiesSummaryTHIOL-ENE BASED FUNCTIONALIZATION OF POLYMERSIntroductionGeneral Considerations and MechanismsFunctionalization of PolymersSummaryTHIOL-YNE CHEMISTRY IN POLYMER AND MATERIALS SCIENCEIntroductionThe Thiol-yne Reaction in Small-Molecule ChemistryThe Thiol-yne Reaction in Polymer and Material SynthesisDESIGN AND SYNTHESIS OF MALEIMIDE GROUP CONTAINING POLYMERIC MATERIALS VIA THE DIELS-ALDER/RETRO DIELS-ALDER STRATEGYIntroductionMaleimide Functional Group Containing Polymeric Materials The Diels-Alder/Retro Diels-Alder Cycloaddition-Cycloreversion Reactions Application of Diels-Alder/Retro Diels-Alder Reaction to Synthesize Maleimide-Containing Polymers Conclusions THE SYNTHESIS OF END-FUNCTIONAL RING-OPENING METATHESIS POLYMERSIntroductionEnd-Functionalization Methods in GeneralFunctionalization during InitiationFunctionalization after PropagationFunctionalization during PropagationConclusions and OutlookFUNCTIONAL POLYMERS WITH CONTROLLED MICROSTRUCTURE BASED ON STYRENE AND N-SUBSTITUTED MALEIMIDESIntroductionBackground on Radical Copolymerization of Styrene and MaleimidesPrecise Incorporation of Maleimide Units on Polystyrene

Patrick Theato is Associate Professor for polymer chemistry at the University of Hamburg. He studied chemistry at Mainz (Germany) and Amherst (USA), and received his Ph.D. in 2001 from the University of Mainz with Prof. R. Zentel. After postdoctoral research with Prof.

D.Y. Yoon (Seoul National University, Korea) and Prof. C.W.. Frank (Stanford University, USA), he joined the University of Mainz as a young faculty member and completed his Habilitation in 2007. From 2009 to 2012 he held a joint appointment with the School of Chemical and Biological Engineering at Seoul National University within the World Class University program. In 2011 he accepted a prize senior lectureship at the University of Sheffield, UK. Shortly after he moved to University of Hamburg, Germany. He serves as an Editorial Advisory Board Member of "Macromolecules". His current research interests include the defined synthesis of reactive polymers, block copolymers, design of multi stimuli-responsive polymers, versatile functionalization of interfaces, hybrid polymers, polymers for electronics and templating of polymers.

Harm-Anton Klok is Full Professor at the Institutes of Materials and Chemical Sciences and Engineering at the Ecole Polytechnique F&##;dérale de Lausanne (EPFL) (Switzerland). He received his Ph.D. in 1997 from the University of Ulm (Germany) after working with Prof. M. Möller. After postdoctoral research with Prof. D. N. Reinhoudt (University of Twente) and Prof. S. I. Stupp (University of Illinois at Urbana-Champaign, USA), he joined the Max Planck Institute for Polymer Research in Mainz (Germany) in early 1999 as a project leader in the group of Prof. K. Müllen. In November 2002, he was appointed to the faculty of EPFL. Harm-Anton Klok is recipient of the 2007Arthur K. Doolittle Award of the American Chemical Society (ACS) and is Associate Editor of the ACS journal "Biomacromolecules".