Catalytic Science Series: Electro-Catalysis at Chemically Modified Solid Surfaces (PDF)

Jacques Simonet received his Ingenieur Chimiste degree from the University of Clermont-Ferrand (France) in 1962 and immediately took a position of Chercheur Scientifique at the Centre National de la Recherche Scientifique (CNRS). He received the Doctorat d'Etat from the same University in 1967, and in 1972, he spent one year as a NATO fellow at the University of Aarhus (Denmark) in the research group of Professor Henning Lund. In 1980, he became Director of Recherche and simultaneously took over the direction of the Electro-chemistry groups at both the University of Rennes (France) and the Catholic University in Angers (France). Dr Simonet has been guest of the Monsanto Company (St Louis, 1976) and of the Electro-synthesis Company (Buffalo, 1993) and has been a visiting faculty member at the University of Aarhus (1974 and 1975) and at the Indiana University, Bloomington (1995, 1998, 1999, 2000, and 2003).

Organic electron-transfer reactions have long been the focus of Dr Simonet's work. In the course of his investigations, he has found new electron-labile protecting groups. In particular, he has made important contributions to the electro-chemistry of organic compounds containing sulfur (sulfones, sulfoxides, and sulfonium derivatives) and nitrogen (amines and sulfonamides). In collaboration with Professor Henning Lund, he discovered redox catalysis in organic chemistry, as well as perturbed redox catalysis in which radical coupling takes place. He was the first to anodically polymerize poly-ethers and crown ethers to generate new materials capable of extracting very low concentrations of heavy-metals and/or radioactive cations from aqueous solutions. His research concerning the insertion and /or intercalation of organic or inorganic cations into graphite and noble metals (platinum and palladium) had led to the development of new kinds of modified solid surfaces.

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