Novel Trends in Electroorganic Synthesis
(Sprache: Englisch)
Among the topics of interest to organic chemists today are the versatility and uniqueness of electrolysis procedures in organic synthesis, as well as the latest advances in methodology, including basic concepts for the design of electrolysis conditions and...
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Among the topics of interest to organic chemists today are the versatility and uniqueness of electrolysis procedures in organic synthesis, as well as the latest advances in methodology, including basic concepts for the design of electrolysis conditions and apparatus. The International Symposium on Electroorganic Synthesis met in Kurashiki, Japan, in September 1997 for lectures on all aspects of current research in the field. This volume comprising the papers from the symposium consists of two parts. Part I, Electrooxidation, includes papers on alcohols and phenols, olefins and aromatics, halogenation, polymers, and electrodes, among others. Included in Part II, Electroreduction, are papers on carbonyl compounds, halogen-containing compounds, reaction with EG bases, and metal complexes. The novel trends presented here will be of special interest to researchers and graduate students in electroorganic chemistry and are a valuable resource for all organic chemists.
Inhaltsverzeichnis zu „Novel Trends in Electroorganic Synthesis “
Electroactivation of Transition Metal Redox Couples for the Carbonylation of Alcohols to Dialkylcarbonates.- Electroorganic Cyclisation of Oxygen-Containing Compounds.- Electrochemical Oxidation of Alcohol with Nickel Hydroxide Electrocatalyst Studied by the in situ Techniques: Infrared Spectroscopy, Potential Modulated Reflectance Spectroscopy and Electrochemical Methods. An Attempt for Electroorganic Synthesis of Organic Acids.- Redox Catalysis of Novel Heterocyclic o-Quinone Coenzymes.- Natural Product Syntheses Using Phenolic Oxidation in the Key Step.- Reactivity of o,o?-Dihalogenated Phenols in Anodic Oxidations.- Electrochemical Synthesis of Euglobal Skeletons via Biomimic Cycloaddition.- Electrochemical Cleavage of Benzylic Single and Double Carbon-Carbon Bonds.- Some Observations on Intermediates of c-Hexene Bifunctionalization.- Formation and Reactivity of Radical Cations of Cyclopropane Derivatives.- Epoxidation of 1,4-Naphthoquinones by Electrochemically Generated Hypohalogen Acids.- Experimental and Theoretical Studies on Preparation of Hydroquinone from Benzene in a Paired Packed-Bed Electrode Reactor.- Useful Electro-Oxidative Conversions of Aromatic Compounds.- The Electrochemical Trifluoromethylation and Perfluoroalkoxylation of Aromatic Compounds.- Anodic Electrochemistry: Recent Advances in the Total Synthesis of Complex Organic Molecules.- Electrogenerated N,O-Acetals in Cyclization and Cycloaddition Reactions.- Anodic Oxydation of Heterocycles: Alkaloids Synthesis.- Iminoquinones as Electrogenerated Electrophilic Species.- The Mechanism of the C-S Bond Cleavage in Electron Transfer Reactions of ?-OrganothioSubstituted Heteroatom Compounds.- Modification of Cephalosporins Bearing Substituents at C(3?)-Position via Electrogenerated Radical-Cation of Sulfide.- Electrolytic C-S Cleavages Giving Rise to Ketones and Carboxylic Acids.- Ring Opening Reaction of Phenylthio-Cyclopropanes by Anodic or Photochemical One-Electron Oxidation.- Addition of
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Electrochemically Generated Chalcogenolate Anions and/or Radicals on the Activated Double Bond.- Anodic Oxidation of Bis(2,6-dimethoxyphenyl)chalcogenides.- Redox Properties of Hydroxyphenyl Nitronyl Nitroxide.- Synthesis of Terminal-Biradical Compounds Consisting of Two N-oxyl Groups Connected with Conjugated ?-systems.- Interfacial Redox Behavior of Mono- and Multilayers of Tetrathiafulvalene Terminated Alkane-Tetrathiol on Gold Electrode.- Electrochemical Reactions of Phosphorous Acid Esters.- Reactions of Electrochemically Generated Alkoxy Phosphonium Ions.- A New Concept and Technology in Electrooxidative Carbon-Carbon Bond Formation.- Anodic Oxidation of Cyclic Organic Polysilanes.- Synthesis, Chemistry, and Anodic Oxidation of 1,2-Bis(trialkylsilyl)ethanes.- Synthesis of Optically Active 1,3-Dienes from Alkenylstannanes by a Combination of Electrooxidation and Copper-Mediated Homocoupling Reaction.- Selective Anodic Fluorination of Heterocycles. Potential Application towards Pharmaceuticals.- Electrochemical Partial Fluorination of ?,?-Unsaturated Esters.- Electro-Oxidation of Enamines Using Iodide Ion as a Mediator.- A Convenient Electrochemical O-Glycosylation of Thioglycoside Using Catalytic Br?.- Indirect Anodic Fluorodesulfurization Using Triarylamine Mediators.- Electrooxidation of Cyclohexanol to Cyclohexanone in the Presence of a Mediatory System.- Electrochemical Oxidation of Diols Mediated by Organotin Compounds.- Photoinduced Electrochemical Oxidation of Alcohols Utilizing Flavin Analog Mediators in Organic Electrolytes.- Application of Transition Metal Substituted ?-Keggin Silicon Polyoxotungstates as Oxidation Electrocatalyst.- New Conducting Polypyrroles Fused with Aromatic Rings.- Electrochemical Cyclooligomerization of 1,4-Bis(1,4-dithiafulven-6-yl)benzene and Analogues.- Rectifying and Photovoltaic Effects of Organic Hetero-Junction Films Based on Fluorenone Derivatives / Poly(3-methylthiophene) Prepared by Electrochemical Polymerization and
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Bibliographische Angaben
- 2013, Softcover reprint of the original 1st ed. 1998, 461 Seiten, Maße: 17 x 24,4 cm, Kartoniert (TB), Englisch
- Herausgegeben: Sigeru Torii
- Verlag: Springer, Berlin
- ISBN-10: 4431659269
- ISBN-13: 9784431659266
Sprache:
Englisch
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