Organic Free Radicals
Proceedings of the Fifth International Symposium, Zürich, 18.-23. September 1988
(Sprache: Englisch)
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Inhaltsverzeichnis zu „Organic Free Radicals “
Thermal Decomposition of Indolinonic Nitroxides. A Kinetic ESR Study.- Radical Cations from Alkyliodides and 1,n-Halogen(Alkylthio)Alkanes in Solution..- Studies of ß -Suifonyl Substituted Vinyl Nitroxides..- Direct and Indirect Diels-Alder Additions to Electron Rich Dienophiles.- Photo-Friedel-Crafts Reaction in Synthesis of Catharanthine and its Derivatives..- Hydroxyl Radical-Induced Strand Break Formation in Single-Stranded Polynucleotides and Single-Stranded DNA in Aqueous Solution as Measured by Light Scattering and by Conductivity..- Cobaloxime-Mediated Radical Cross Coupling Reactions..- Magnetic Effects in the Photochemistry of Ketones.- ESR Study of Reactive Intermediates in the Radiolysis and Photolysis of Al Alkoxides.- Rate Constants for Electron Transfer and Radical Cation Reactions of Methylated Naphthalenes..- Cyclopentane Ring Formation in the Cycloaddition Reactions of 3-Butenyl Radical on the Electron-Deficient Olefins..- ?-Halosulfones Reduction Mechanism: Application of Highly Efficient Radical Clocks.- Tris(Trimethylsilyl)Silane. A New Reducing Agent.- Autoxidation of (Me3 Si)3SiH.- Ti (III) Salt Mediated Radical Addition to Carbonyl Carbon. Synthesis of ?, ? - Dihydroxyketones.- Polarized EPR Spectra of Unstable Biradicals..- Atom-Transfer Addition, Cyclization and Annulation..- Mercuric Oxide - Iodine Oxidation of Steroidal Homoallylic Alcohols.- The Mechanisms of the Rearrangements of Allylic Hydroperoxides.- Stereoselective C-C Bond Formation in Carbohydrates by Radical Cyclization Reactions.- A Novel Reaction of Tetracyanoethylene with N-Aryl-Isoindolines.- An Electron Transfer Initiated Isomerization and Solvent Addition via Radical Cation Chain Process.- Tetramethyleneethanes: Non-Kekulé Ground State Triplets at Odds with Theory.- Hydrophobic Radical-Ions..- Simple Synthesis of Nitroxyl Amines..- Micellar Aggregation and the Decay of Triplet Radical Pairs.- Spin Trapping and Matrix Isolation E.S.R. Studies of Photo-Oxidation of Alcohols
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by Hexachlorometallate (IV) Ions (M=Pt, Pd, Ir)..- ESR of Free Radicals in Gamma Irradiated DNA-Histone Complex..- An ESR Investigation of the Photolysis of Benzene Polycarboxylate Anions in Aqueous Solution..- The Effect of Temperature in the Addition of Tosyl Radicals to Arylacetylenes..- Chemical Routes to Atomic Nitrogen..- Hydrogen Atom Abstraction from a Molybdenum Hydride: Radical Clock Studies..- Radical Cyclization of Aldehydes: Synthetic and Mechanistic Developments..- Radical Addition of Acetone to Limonene Initiated by KMnO4 in Acetic Acid Medium..- Three Paramagnetic Reduction Stages of Phenyl Substituted 1,2:9,10-Dibenzo[2.2]Paracyclophanes..- The Role of Solvent Dynamics in Inter- and Intramolecular Electron Exchange Reactions..- On the Radicalic Methylation. Unexpected Formation of Sulfones and Sulfonamides in the Reaction of Nitrosoarenes with Fenton's Reagent in DMSO..- Theoretical Study on the Structure of ?-Substituted Ethyl Radicals..- Radical Reactions for Use in Organic Synthesis.- Free and Unfree Radical Ions..- On the Stabilization of ? - Carbon Radicals by II- and Methylthio-Substituents..- SEESR of Radical-Ions and of Paramagnetic Complexes..- ESR Studies of 1-Silacycloalkyl and 1-Sila-Allyl Radicals..- Photosensitized Generation of Singlet Oxygen (1?g) in Vivo. Proposed Biomedical Applications..- CIDNP in the Reactions of Photooxidation of Benzylic Acid and Phenols Sensitized by Uranyl Ion..- Stereochemical Aspects of Radical Hydroxylation of Cyclohexenes in Aqueous Solution..- Regeneration of Amine in Catalytic Inhibition of Oxidation.- EPR Spectra and Kinetics of some Carbonyloxyl Radicals, XCO2.- The Structure of Co(II)-Corrins - 'Nature's Traps' for Organic Radicals.- Aspects of Organometallic Free Radical Chemistry.- ENDOR Investigations on the Substituent Dependence of the Stabilisation of Triphenylmethyl Radicals..- Hydrogen Atom Transfer between Ketyl Radicals and Ketones.- Formation of Dibenzodioxins and Dibenzofurans in Homogenous Gas-Phase Reactions of Phenols.- Fragmentation Patterns for Anion Radicals in Carboxylic Acids.- Unusual Transannular Radical Cyclisations.- CIDNP during the Oxidation of Tertiary Aliphatic Amines.- Charge Transfer Interaction between Menadione and Nucleic Acids. A CIDNP Study.- Grignard Reaction of Ketones. Electron and Subsequent R Transfer Processes to Ketones.- Radical Ions and Photochemical Charge Transfer Phenomena in Organic Chemistry.- Cyclisation of ?-Arylalkanols via Aryl Radical-Cation and Alkoxyl Radical Intermediates..- The Question of Additivity of Substituent Effects on Radical Stabilisation..- Spin Delocalisation in Heterocyclic Captodative Radicals..- ? - Fragmentation of Alkyl Radicals. Polar and Steric Effects.- The Decay Kinetics of Triplet-Triplet Fluorescence Systems. The m-Xylylene Biradicals..- ESR Spectroscopy of Short-Lived Radical Pairs in Solutions..- Stereochemical Effect on Intramolecular Substitutions in Induced Decomposition o
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Bibliographische Angaben
- 1988, 251 Seiten, Maße: 24,4 cm, Kartoniert (TB), Englisch
- Ed. by Fischer, Hanns; Heimgartner, Heinz
- Verlag: Springer
- ISBN-10: 3540501290
- ISBN-13: 9783540501299
Sprache:
Englisch
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