Wegner, H: Studies on Rhodium-Catalyzed (5+2) Cocyclization
The first part of this thesis dealt with the a new kind of precursors for transition metalcatalyzed cocyclization reactions containing a vinylbicyclopropyl unit, their synthesis and their behavior in cocyclization reactions. By introducing a second...
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The first part of this thesis dealt with the a new kind of precursors for transition metalcatalyzed cocyclization reactions containing a vinylbicyclopropyl unit, their synthesis and their behavior in cocyclization reactions. By introducing a second cyclopropane the catalyst might open this ring as well after insertion into the first cyclopropane ring. The ¿basic¿ formal (5+2) cycloaddition reaction would be extended to a (5+2+3) cocyclization reaction to form ten-membered rings. In addition to the importance as a new synthetic tool valuable insights into the mechanism of transition metal-catalyzed cocyclization reactions of vinylcyclopropanes are gained.
Bibliographische Angaben
- Autor: Hermann Wegner
- X, 199 Seiten, Maße: 14,6 x 20,8 cm, Kartoniert (TB), Deutsch
- Verlag: Cuvillier Verlag
- ISBN-10: 3865372090
- ISBN-13: 9783865372093
- Erscheinungsdatum: 20.09.2004
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