Aziridines and Epoxides in Organic Synthesis (PDF)

ASYMMETRIC SYNTHESIS OF EPOXIDES AND AZIRIDINES FROM ALDEHYDES AND IMINES Asymmetric Epoxidation of Carbonyl Compounds Asymmetric Aziridination of Imines VINYLAZIRIDINES IN ORGANIC SYNTHESIS Direct Synthesis of Vinylaziridines Ring-opening Reactions with Nucleophiles Isomerization Including Rearrangement Cycloaddition Electron Transfer to Vinylaziridines ASYMMETRIC SYNTHESES WITH AZIRIDINECARBOXYLATE AND AZIRIDINEPHOSPHONATE BUILDING BLOCKS Preparation of Aziridine-2-carboxylates and Aziridine-2-phosphonates Reactions of Aziridine-2-carboxylates and Aziridine-2-phosphonates Applications in Natural Product Syntheses SYNTHESIS OF AZIRIDINES Overview and General Features METALATED EPOXIDES AND AZIRIDINES IN SYNTHESIS Metalated Epoxides Metalated Aziridines METAL-CATALYZED SYNTHESIS OF EPOXIDES Oxidants Available for Selective Transition Metal-catalyzed Epoxidation Epoxidations of Olefins Catalyzed by Early Transition Metals Chromium-, Molybdenum-, and Tungsten-catalyzed Epoxidations Manganese-catalyzed Epoxidations Rhenium-catalyzed Epoxidations Iron-catalyzed Epoxidations Ruthenium-catalyzed Epoxidations CATALYTIC ASYMMETRIC EPOXIDE RING-OPENING CHEMISTRY Enantioselective Nucleophilic Addition to Meso-Epoxides Kinetic Resolution of Racemic Epoxides Enantioselective Rearrangements of Epoxides EPOXIDES IN COMPLEX MOLECULE SYNTHESIS Synthesis of Complex Molecules by Intramolecular Ring-opening of Epoxides with Heteronucleophiles Synthesis of Complex Molecules by Ring-opening of Epoxides with C-Nucleophiles Epoxy Glycals Synthesis of Complex Molecules by Rearrangement Reactions of Epoxides VINYLEPOXIDES IN ORGANIC SYNTHESIS Synthesis of Vinylepoxides Transformations of Vinylepoxides THE BIOSYNTHESIS OF EPOXIDES Cytochrome P450 Monooxygenases Flavin-dependent Epoxidases Dioxygenases Epoxidation through Dehydrogenation Dehalogenases AZIRIDINE NATURAL PRODUCTS - DISCOVERY, BIOLOGICAL ACTIVITY AND BIOSYNTHESIS Mitomycins and Related Natural Products The Azinomycins Other

Professor Andrei K. Yudin obtained his PhD degree at the University of Southern California under the direction of Professors G. K. Surya Prakash and George A. Olah. He then took up a post-doctoral position in the laboratory of Professor K. Barry Sharpless at the Scripps Research Institute. In 1998, he started his independent career at the University of Toronto. His research interests are in transition metal catalysis, development of novel synthetic methods, and synthesis of complex heterocycles of biological significance.

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