Catalysis
From Principles to Applications
(Sprache: Englisch)
Catalysis has revolutionized the chemical industry as catalysts are used in the production of most chemicals, resulting in a multi-billion
euro business. This advanced textbook is a must-have for all Master and PhD students in the field as it adopts a...
euro business. This advanced textbook is a must-have for all Master and PhD students in the field as it adopts a...
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Produktinformationen zu „Catalysis “
Catalysis has revolutionized the chemical industry as catalysts are used in the production of most chemicals, resulting in a multi-billion
euro business. This advanced textbook is a must-have for all Master and PhD students in the field as it adopts a unique interdisciplinary approach to the topic of catalysis.
euro business. This advanced textbook is a must-have for all Master and PhD students in the field as it adopts a unique interdisciplinary approach to the topic of catalysis.
Klappentext zu „Catalysis “
Catalysis has revolutionized the chemical industry as catalysts are used in the production of most chemicals, resulting in a multi-billioneuro business. This advanced textbook is a must-have for all Master and PhD students in the field as it adopts a unique interdisciplinary approach to the topic of catalysis. It presents a collection of chapters that explain the fundamentals of catalysis as the area has developed over the past decades and introduces new catalytic systems that are of becoming of increasing current importance.It covers all the essential principles, ranging from catalytic processes at the molecular level to catalytic reactor design and includes severalcase studies illustrating the importance of catalysts in the chemical industry.
Inhaltsverzeichnis zu „Catalysis “
PREFACEPART I: Basic ConceptsCATALYSIS IN PERSPECTIVE: HISTORIC REVIEWHistory of Catalysis ScienceThe Development of Catalytic Processes: History and FutureFundamental Catalysis in PracticeCatalyst SelectionReactor ChoiceProcess ChoiceKINETICS OF HETEROGENEOUS CATALYTIC REACTIONSPhysical chemical principlesThe Lock and Key Model, the Role of Adsorption EntropyEquivalence of Electrocatalysis and ChemocatalysisMicrokinetics; the Rate-Determining StepElementary Rate Constant Expressions for Surface ReactionsThe Pressure GapThe Materials GapCoupling of Catalytic Reaction and Inorganic Solid ChemistryIn situ Generation of Organo-CatalystThe Compensation EffectKINETICS IN HOMOGENEOUS CATALYSISPrinciples of a Catalyst and Kinetic DescriptionCatalyst ActivityCatalyst Activation and DeactivationCATALYTIC REACTION ENGINEERING PRINCIPLESPrefaceFormal Kinetics of Catalytic ReactionsMass and Heat Transfer EffectsHomogenous Catalysis in Biphasic Fluid/Fluid SystemsPART II: The Chemistry of Catalytic ReactivityHETEROGENEOUS CATALYSISGeneral IntroductionTransition Metal CatalysisSolid Acids and BasesReducible OxidesHOMOGENEOUS CATALYSISGeneral FeaturesBIOCATALYSISIntroductionExamplesSummary/ConclusionsELECTROCATALYSISIntroductionTheoryApplication to the Oxygen Reduction Reaction (ORR) on Pt(111)SummaryHETEROGENEOUS PHOTOCATALYSISIntroductionApplications of PhotocatalysisCase StudiesConcluding RemarksPART III: Industrial Catalytic ConversionsCARBONYLATION REACTIONSGeneral AspectsHydroformylationOther Carbonylations of Olefins and AlkynesCarbonylations of Alcohols and Aryl HalidesBIOCATALYTIC PROCESSESIntroductionExamplesCase Study: Synthesis of Lipitor Building BlocksConclusionsPOLYMERIZATIONIntroductionPolyolefins in BriefOlefin Polymerization CatalystsOlefin Polymerization Process TechnologyThe Latest BreakthroughsAMMONIA SYNTHESISAmmonia PlantSynthesisSteam ReformingConclusionsFISCHER-TROPSCH SYNTHESIS IN A MODERN PERSPECTIVEIntroductionStoichiometry and Thermodynamic
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AspectsProcesses and Product CompositionCatalysts, GeneralReaction FundamentalsConcluding RemarksZEOLITE CATALYSISIntroductionThe Hydrocracking Reaction; Acid CatalysisLewis Acid - Lewis Base Catalysis; Hydrocarbon ActivationSelective Oxidation; Redox CatalysisFramework-Substituted Redox IonsCATALYTIC SELECTIVE OXIDATION - FUNDAMENTALS, CONSOLIDATED TECHNOLOGIES, AND DIRECTIONS FOR INNOVATIONCatalytic Selective Oxidation: Main FeaturesCatalytic Selective Oxidation: What Makes the Development of an Industrial Process More Challenging (and Troublesome) than Other ReactionsCatalytic Selective Oxidation: the Forefront in the Continuous Development of More-Sustainable Industrial TechnologiesThe Main Issue in Catalytic Oxidation: the Control of SelectivityDream Reactions in Catalytic Selective Oxidation: a Few Examples (Some Sustainable, Some Not Sustainable)A New Golden Age for Catalytic Selective Oxidation?Conclusions: Several Opportunities for More Sustainable Oxidation ProcessesHIGH-TEMPERATURE CATALYSIS: ROLE OF HETEROGENEOUS, HOMOGENEOUS, AND RADICAL CHEMISTRYIntroductionFundamentalsApplicationsHydrogen Production from Logistic Fuels by High-Temperature CatalysisHigh-Temperature Catalysis in Solid Oxide Fuel CellsHYDRODESULFURIZATIONIntroductionHydrodesulfurizationThe C-X Bond-Breaking MechanismStructure of the Sulfidic CatalystHydrodenitrogenationDetermination of Surface SitesPART IV: Catalyst Synthesis and MaterialsMOLECULARLY DEFINED SYSTEMS IN HETEROGENEOUS CATALYSISIntroductionSingle Sites: On the Border between Homogeneous and Heterogeneous CatalysisConclusion and PerspectivesPREPARATION OF SUPPORTED CATALYSTSIntroductionSupport Surface ChemistryIon AdsorptionImpregnation and DryingDeposition PrecipitationThermal TreatmentPOROUS MATERIALS AS CATALYSTS AND CATALYST SUPPORTSGeneral CharacteristicsSol-gel and Fumed SilicaAlumina and Other OxidesCarbon MaterialsZeolitesOrdered Mesoporous MaterialsMetal-Organic FrameworksShapingDEVELOPMENT OF CATALYTIC MATERIALSIntroductionFundamental AspectsMicro-Kinetics and Solid-State Properties as a Knowledge Source in Catalyst DevelopmentCombinatorial Approaches and High-Throughput Technologies in the Development of Solid CatalystsPART V: Characterization MethodsIN-SITU TECHNIQUES FOR HOMOGENEOUS CATALYSISIntroductionIn-situ Techniques for Homogeneous CatalysisGas Consumption and Gas FormationNMR SpectroscopyIR-SpectroscopyUV/Vis SpectroscopySummaryIN-SITU CHARACTERIZATION OF HETEROGENEOUS CATALYSTSIntroductionSome History, Recent Developments, and ApplicationsIn situ Characterization of a Reactor Loaded with a Catalytic SolidIn situ Characterization at a Single Catalyst Particle LevelConcluding RemarksADSORPTION METHODS FOR CHARACTERIZATION OF POROUS MATERIALSIntroductionPhysical AdsorptionClassification of Porous MaterialsAdsorption IsothermsThe Application of Adsorption MethodsTheoretical Description of AdsorptionCharacterization of Microporous MaterialsCharacterization of Mesoporous MaterialsMercury PorosimetryXenon PorosimetryA CRITICAL REVIEW OF SOME "CLASSICAL" GUIDELINES FOR CATALYST TESTINGIntroductionEncouraging EffectivenessEnsuring EfficiencyConcluding RemarksAPPENDIX A: THREE-PHASE TRICKLE-BED REACTORSPART VI: Catalytic Reactor EngineeringCATALYTIC REACTOR ENGINEERINGIntroductionTypes of Catalytic ReactorsIdeal Reactor Modeling/Heat ManagementResidence Time DistributionMicro Reaction Engineering
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Autoren-Porträt
Matthias Beller obtained his PhD at the University of Göttingen, Germany and completed a postdoctoral fellowship at the Massachusetts Institute of Technology in Cambridge, USA. Since 1998, he has been head of the Leibniz Institute for Organic Catalysis at University ofRostock. He is a member of the board of Dechema`s Catalysis Section, the German Catalysis Competence Network ('ConNeCat') as well as the Innovationsagentur Mecklenburg-Vorpommern. He is also a member of the Association for Technical Sciences of the Union ofGerman Academies of Sciences and Humanities.Albert Renken obtained his academic degrees at the Technical University of Hanover, Germany. Professor Renken has been affiliated with ETH Lausanne, Switzerland since 1977. He is author of over 450 scientific publications in journals and author or editor of 5 books andof numerous patents. From 1992 to 2000, Albert Renken was science councillor of the Swiss National Science Foundation (SNF), and from 1996 to 2000 he served as chairman of the European Federation of Chemical Reaction Engineering Working Party. He is also member ofthe Swiss Academy of Engineering Sciences.Rutger Anthony van Santen obtained his doctorate at the University of Leiden, Netherlands. After an initial career at Shell Research in 1988, he joined Eindhoven University of Technology as a Professor of Catalysis. In 1991 he became director of the Netherlands Institute of Researchin Catalysis, and in 2005 he was made Royal Netherlands Academy of Science and Arts Professor. He is a member of the Royal Dutch Academy of Arts and Sciences, Dutch Academy of Engineering and is a Knight in the order of the Dutch Lion. Professor van Santen is theauthor or editor of 13 books, over 700 research papers and 22 patents, and has been awarded several national and international awards and visiting professorships.
Bibliographische Angaben
- 2012, 1. Auflage, XXII, 642 Seiten, 26 farbige Abbildungen, 262 Schwarz-Weiß-Abbildungen, Maße: 17,6 x 24,6 cm, Gebunden, Englisch
- Herausgegeben: Matthias Beller, Albert Renken, Rutger A. VanSanten
- Verlag: Wiley-VCH
- ISBN-10: 352732349X
- ISBN-13: 9783527323494
- Erscheinungsdatum: 14.08.2012
Sprache:
Englisch
Rezension zu „Catalysis “
"Overall, this is a useful book for process chemists with the reservation that modern carbon-carbon bond forming catalytic reactions (Buchwald-Hartwig, Suzuki-Miyaura, Heck etc) are not covered. The emphasis is definitely towards heterogenous catalysis." ( Organic Process Research & Development Journal , 1 November 2012)
Pressezitat
"Overall, this is a useful book for process chemists with the reservation that modern carbon-carbon bond forming catalytic reactions (Buchwald-Hartwig, Suzuki-Miyaura, Heck etc) are not covered. The emphasis is definitely towards heterogenous catalysis." ( Organic Process Research & Development Journal , 1 November 2012)Kommentar zu "Catalysis"
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