Electron Nuclear Double Resonance Spectroscopy of Radicals in Solution

Preface
Symbols, Abbreviations, Conversion of Units
1 Introduction
2 Principles of Multiple Electron-Nuclear Resonance Techniques
2.1 Principles of ENDOR Spectroscopy
2.2 Electron-Nuclear-Nuclear Triple Resonance Spectroscopy
2.3 ENDOR-Induced EPR Spectroscopy (EIE)
2.4 ENDOR Instrumentation
2.5 Sample Preparation
3 Theoretical Aspects of ENDOR Spectroscopy
3.1 Contributions to the General Hamiltonian
3.2 Phenomenological Theory of the ENDOR Effect: Electric-Circuit Analogy
3.3 Special Effects in ENDOR Spectroscopy
3.4 Density-Matrix Treatment of the ENDOR Effect
3.5 Summary
4 ENDOR Spectroscopy of Nuclei Other than Protons (Nonproton ENDOR)
4.1 Nuclear Properties Influencing the ENDOR Effect
4.2 2H ENDOR Spectroscopy
4.3 13C ENDOR Spectroscopy
4.4 14N ENDOR Spectroscopy
4.5 15N ENDOR Spectroscopy
4.6 19F ENDOR Spectroscopy
4.7 ENDOR Spectroscopy of Alkali Nuclei
4.8 31P ENDOR Spectroscopy
4.9 10B and 11B ENDOR Spectroscopy4.10 27Al ENDOR Spectroscopy
4.11 29Si ENDOR Spectroscopy
4.12 25Mg ENDOR Spectroscopy
4.13 203Tl and 205Tl ENDOR Spectroscopy
4.14 117Sn and 119Sn ENDOR Spectroscopy
4.15 Other Magnetic Nuclei
5 Organic Doublet Radicals Studied by ENDOR in Solution
5.1 Carbon-Centered Neutral Radicals and Radical Ions
5.2 Oxygen-Centered Neutral Radicals and Radical Ions
5.3 Nitrogen-Centered Neutral Radicals and Radical Ions
5.4 Silicon-Centered Radical Ions
5.5 Free-Radical States of Organic Metal Complexes and Ion Pairs
6 ENDOR Studies of Intramolecular Dynamic Processes
6.1 Theoretical Aspects
6.2 Studies of Jump Processes
6.3 Studies of Temperature-Dependent -Proton Couplings
7 ENDOR Investigations in Liquid-Crystalline Solutions
7.1 Theoretical Aspects
7.2 Studies of Phenalenyls-Ordering and Alignment
7.3 Studies of Other Doublet Radicals
8 ENDOR Spectroscopy of Organic Multispin Systems
8.1 Theoretical Aspects
8.2 Studies of Multispin Systems in Fluid Solution
8.3 Studies of Multispin Systems in Rigid Media
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