ENOLIZATION REACTIONS MEDIATED BY S-BLOCK METAL AMIDE REAGENTS
Performance of Alkali and Alkaline Earth Metal Amides in Enolization of Ketones and the Mechanism behind E-stereoselectivity in non-polar solvents
(Sprache: Englisch)
The enolization of ketonic substrates is a cornerstone reaction in modern organic synthesis. The research in this book is split into three main sections, with the investigation of s-block metal enolate chemistry being the underlying theme: The first section...
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The enolization of ketonic substrates is a cornerstone reaction in modern organic synthesis. The research in this book is split into three main sections, with the investigation of s-block metal enolate chemistry being the underlying theme: The first section focuses on the synthesis and characterization of a series of homo- and heterobimetallic potassium and calcium enolates. The second section concentrates on an investigation into the utility of Ca(HMDS)2 to mediate the enolization of ketonic substrates. The final section outlines a detailed mechanistic study for the enolization of propiophenone mediated by Mg(HMDS)2 in toluene.
Autoren-Porträt von Xuyang He
He, XuyangXuyang He obtained her Ph.D.degree in Organometallic Chemistry atUniversity of Notre Dame in 2008.
Bibliographische Angaben
- Autor: Xuyang He
- 2009, 220 Seiten, Maße: 22 cm, Kartoniert (TB), Englisch
- Verlag: LAP Lambert Academic Publishing
- ISBN-10: 3838300165
- ISBN-13: 9783838300160
Sprache:
Englisch
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