Handbook of Green Chemistry - Green Catalysis

ATOM ECONOMY - PRINCIPLES AND SOME EXAMPLESIntroductionPrinciple of Atom EconomyAtom Economical by Design: Examples of Reactions Relying on C-H ActivationConclusionCATALYSIS INVOLVING FLUOROUS PHASES: FUNDAMENTALS AND DIRECTIONS FOR GREENER METHODOLOGIESIntroductionDirections for Greener Fluorous MethodologiesSolvents for Fluorous ChemistryPonytails and Partition CoefficientsSpecific Examples of Catalyst Recovery that Exploit Temperature-dependent SolubilitiesSpecific Examples of Catalyst Recovery that Exploit Fluorous Solid PhasesSummary and PerspectiveCHEMISTRY AND APPLICATIONS OF IRON-TAML CATALYSTS IN GREEN OXIDATION PROCESSES BASED ON HYDROGEN PEROXIDEIntroductionProperties of Fe-TAMLs and Mechanisms of Oxidation with Hydrogen PeroxideApplications of Fe-TAMLsConclusionMICROWAVE-ACCELERATED HOMOGENEOUS CATALYSIS IN WATERIntroductionSuzuki-Miyaura ReactionsThe Stille ReactionThe Hiyama Cross-Coupling ReactionThe Heck ReactionCarbonylation ReactionsThe Sonogashira ReactionAryl-Nitrogen CouplingsAryl-Oxygen CouplingsMiscellaneous TransformationsConclusionIONIC LIQUIDS AND CATALYSIS: THE IFP BIPHASIC DIFASOL PROCESSIntroductionThe Solvent in Catalytic ReactionsThe Catalytic Oligomerization of OlefinsThe Biphasic Difasol ProcessConclusionIMMOBILIZATION AND COMPARTMENTALIZATION OF HOMOGENEOUS CATALYSTSIntroductionSoluble Dendrimer-bound Homogeneous CatalystsPolymer-bound Homogeneous CatalystsConclusion and OutlookINDUSTRIAL APPLICATIONS OF HOMOGENEOUS ENANTIOSELECTIVE CATALYSTSIntroduction and ScopeCritical Factors for the Technical Application of Homogeneous Enantioselective CatalystsIndustrial Processes: General CommentsHydrogenation of C=C BondsHydrogenation of C=O BondsHydrogenation of C=N BondsOxidation ProcessesMiscellaneous Transformations (Isomerization, Addition Reactions to C=C, C=O and C=N Bonds, Opening of Oxacycles)Conclusions and Future DevelopmentsHYDROGENATION FOR C-C BOND FORMATIONBy-product-free C-C Coupling and the Departure from Preformed

Series EditorPaul T. Anastas joined Yale University as Professor and serves as the Director of the Center for Green Chemistry and Green Engineering at Yale. From 2004-2006, Paul Anastas has been the Director of the Green Chemistry Institute in Washington, D.C. Until June of 2004 he served as Assistant Director for Environment at e White House Office of Science and Technology Policy where his responsibilities included a wide range of environmental science issues including furthering international public-private cooperation in areas of Science for Sustainability such as Green Chemistry. In 1991, he established the industry-government-university partnership Green Chemistry Program, which was expanded to include basic research, and the Presidential Green Chemistry Challenge Awards. He has published and edited several books in the field of Green Chemistry and is one of the inventors of the 12 principles of Green Chemistry.Volume EditorBob Crabtree took his first degree at Oxford, did his Ph.D. at Sussex and spent four years in Paris at the CNRS. He has been at Yale since 1977. He has chaired the Inorganic Division at ACS, and won the ACS and RSC organometallic chemistry prizes. He is the author of an organometallic textbook, and editor-in-chief of the Encyclopedia of Inorganic Chemistry and Comprehensive Organometallic Chemistry. He has contributed to C-H activation, H2 complexes, dihydrogen bonding, and his homogeneous tritiation and hydrogenation catalyst is in wide use. More recently, he has combined molecular recognition with CH hydroxylation to obtain high selectivity with a biomimetic strategy.