Multilayer Thin Films
Sequential Assembly of Nanocomposite Materials. Forew. by Jean-Marie Lehn
(Sprache: Englisch)
This second, comprehensive edition of the pioneering book in this field has been completely revised and extended, now stretching to two volumes. The result is a comprehensive summary of layer-by-layer assembled, truly hybrid nanomaterials and thin films,...
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Produktinformationen zu „Multilayer Thin Films “
This second, comprehensive edition of the pioneering book in this field has been completely revised and extended, now stretching to two volumes. The result is a comprehensive summary of layer-by-layer assembled, truly hybrid nanomaterials and thin films, covering organic, inorganic, colloidal, macromolecular and biological components, plus the assembly of nanoscale films derived from them on surfaces. For anyone working in the field as well as scientists and researchers active in materials development who need the key knowledge provided here for linking the fields of molecular self-assembly with materials- and biosciences.
Klappentext zu „Multilayer Thin Films “
This second, comprehensive edition of the pioneering book in this fi eld has been completely revised and extended, now stretching to twovolumes. The result is a comprehensive summary of layer-by-layer assembled, truly hybrid nanomaterials and thin fi lms, covering organic,
inorganic, colloidal, macromolecular, and biological components, as well as the assembly of nanoscale fi lms derived from them on surfaces.
These two volumes are essential for anyone working in the field, as well as scientists and researchers active in materials development, who
needs the key knowledge provided herein for linking the field of molecular self-assembly with the bio- and materials sciences.
Inhaltsverzeichnis zu „Multilayer Thin Films “
VOLUME 1LAYER-BY-LAYER ASSEMBLY (PUTTING MOLECULES TO WORK)
The Whole is More than the Sum of its Parts
From Self-Assembly to Directed Assembly
History and Development of the Layer-by-Layer Assembly Method
LbL-Assembly is the Synthesis of Fuzzy Supramolecular Objects
Reproducibility and Choice of Deposition Conditions
Monitoring Multilayer Build-up
Spray- and Spin-Assisted Multilayer Assembly
Recent Developments
Final Remarks
PART I: Preparation and Characterization
LAYER-BY-LAYER PROCESSED MULTILAYERS: CHALLENGES AND OPPORTUNITIES
Introduction
Fundamental Challenges and Opportunities
The Path Forward
LAYER-BY-LAYER ASSEMBLY: FROM CONVENTIONAL TO UNCONVENTIONAL METHODS
Introduction
Conventional LbL Methods
Unconventional LbL Methods
Summary and Outlook
NOVEL MULTILAYER THIN FILMS: HIERARCHIC LAYER-BY-LAYER (HI-LBL) ASSEMBLIES
Introduction
Hi-LbL for Multi-Cellular Models
Hi-LbL for Unusual Drug Delivery Modes
Hi-LbL for Sensors
Future Perspectives
LAYER-BY-LAYER ASSEMBLY USING HOST-GUEST INTERACTIONS
Introduction
Supramolecular Layer-by-Layer Assembly
3D Patterned Multilayer Assemblies on Surfaces
3D Supramolecular Nanoparticle Crystal Structures
Porous 3D Supramolecular Assemblies in Solution
Conclusions
LBL ASSEMBLIES USING VAN DER WAALS OR AFFINITY INTERACTIONS AND THEIR APPLICATIONS
Introduction
Stereospecific Template Polymerization of Methacrylates by Stereocomplex Formation in Nanoporous LbL Films
Preparation and Properties of Hollow Capsules Composed of Layer-by-Layer Polymer Films Constructed through van der Waals Interactions
Fabrication of Three-Dimensional Cellular Multilayers Using Layer-by-Layer Protein Nanofilms Constructed through Affinity Interaction
Conclusion
LAYER-BY-LAYER ASSEMBLY OF POLYMERIC COMPLEXES
Introduction
Concept of LbL Assembly of Polymeric Complexes
Structural Tailoring of LbL-Assembled Films of Polymeric
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Complexes
LbL-Assembled Functional Films of Polymeric Complexes
Summary
MAKING AQUEOUS NANOCOLLOIDS FROM LOW SOLUBILITY MATERIALS: LBL SHELLS ON NANOCORES
Introduction
Formation of Nanocores
Ultrasonication-Assisted LbL Assembly
Solvent-Assisted Precipitation Into Preformed LbL-Coated Soft Organic Nanoparticles
Washless (Titration) LbL Technique
Formation of LbL Shells on Nanocores
Drug Release Study
Conclusions
CELLULOSE FIBERS AND FIBRILS AS TEMPLATES FOR THE LAYER-BY-LAYER (LBL) TECHNOLOGY
Background
Formation of LbLs on Cellulose Fibers
The use of LbL to Improve Adhesion between Wood Fibers
The Use of LbL to Prepare Antibacterial Fibers
The use of NFC/CNC to Prepare Interactive Layers Using the LbL Approach
Conclusions
FREELY STANDING LBL FILMS
Introduction
Fabrication of Freely Standing Ultrathin LbL Films
Porous and Patterned Freely Standing LbL Films
Freely Standing LbL Films with Weak Interactions
NEUTRON REFLECTOMETRY AT POLYELECTROLYTE MULTILAYERS
Introduction
Neutron Reflectometry
Preparation Techniques for Polyelectrolyte Multilayers
Types of Polyelectrolytes
Preparation Parameters
Influence of External Fields After PEM Assembly
PEM as a Structural Unit
Conclusion and Outlook
POLYELECTROLYTE CONFORMATION IN AND STRUCTURE OF POLYELECTROLYTE MULTILAYERS
Introduction
Results
Conclusion and Outlook
CHARGE BALANCE AND TRANSPORT IN ION-PAIRED POLYELECTROLYTE MULTILAYERS
Introduction
Association Mechanism: Competitive Ion Pairing
Surface versus Bulk Polymer Charge
Polyelectrolyte Interdiffusion
Ion Transport Through Multilayers: the "Reluctant" Exchange Mechanism
Concluding Remarks
CONDUCTIVITY SPECTRA OF POLYELECTROLYTE MULTILAYERS REVEALING ION TRANSPORT PROCESSES
Introduction t
LbL-Assembled Functional Films of Polymeric Complexes
Summary
MAKING AQUEOUS NANOCOLLOIDS FROM LOW SOLUBILITY MATERIALS: LBL SHELLS ON NANOCORES
Introduction
Formation of Nanocores
Ultrasonication-Assisted LbL Assembly
Solvent-Assisted Precipitation Into Preformed LbL-Coated Soft Organic Nanoparticles
Washless (Titration) LbL Technique
Formation of LbL Shells on Nanocores
Drug Release Study
Conclusions
CELLULOSE FIBERS AND FIBRILS AS TEMPLATES FOR THE LAYER-BY-LAYER (LBL) TECHNOLOGY
Background
Formation of LbLs on Cellulose Fibers
The use of LbL to Improve Adhesion between Wood Fibers
The Use of LbL to Prepare Antibacterial Fibers
The use of NFC/CNC to Prepare Interactive Layers Using the LbL Approach
Conclusions
FREELY STANDING LBL FILMS
Introduction
Fabrication of Freely Standing Ultrathin LbL Films
Porous and Patterned Freely Standing LbL Films
Freely Standing LbL Films with Weak Interactions
NEUTRON REFLECTOMETRY AT POLYELECTROLYTE MULTILAYERS
Introduction
Neutron Reflectometry
Preparation Techniques for Polyelectrolyte Multilayers
Types of Polyelectrolytes
Preparation Parameters
Influence of External Fields After PEM Assembly
PEM as a Structural Unit
Conclusion and Outlook
POLYELECTROLYTE CONFORMATION IN AND STRUCTURE OF POLYELECTROLYTE MULTILAYERS
Introduction
Results
Conclusion and Outlook
CHARGE BALANCE AND TRANSPORT IN ION-PAIRED POLYELECTROLYTE MULTILAYERS
Introduction
Association Mechanism: Competitive Ion Pairing
Surface versus Bulk Polymer Charge
Polyelectrolyte Interdiffusion
Ion Transport Through Multilayers: the "Reluctant" Exchange Mechanism
Concluding Remarks
CONDUCTIVITY SPECTRA OF POLYELECTROLYTE MULTILAYERS REVEALING ION TRANSPORT PROCESSES
Introduction t
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Autoren-Porträt
Gero Decher is a Distinguished Professor of Chemistry at the University of Strasbourg, France, a senior member of the Institut Universitaire de France (IUF) and a member of the International Center for Frontier Research in Chemistry. His research team is located at CNRS Institut Charles Sadron in Strasbourg where he continues to develop the layer-by-layer assembly method in collaboration with his colleagues Pierre Schaaf and Jean-Claude Voegel. This method is applied in many laboratories world-wide in various scientific disciplines, including chemistry, materials science and biotechnology. Gero Decher has received numerous awards, including the ECIS-Rhodia prize in 2010 and the Grand Prix of the French "Académie des Sciences" for Nanobiotechnology in 2009.Joseph B. Schlenoff is Mandelkern Professor of Polymer Science of the Department of Chemistry and Biochemistry at the Florida State University, USA. His laboratory is engaged in multidisciplinary research centered on the use of novel structures made from polyelectrolytes that are deposited using the layer-by-layer technique. His work, supported by the National Science Foundation and the National Institutes of Health, among others, focuses on fundamental polymer science aspects of polyelectrolyte complexes and on their interactions with biological materials. In 2011, Joseph Schlenoff received a Gutenburg Chair at the University of Strasbourg.
Bibliographische Angaben
- 2012, 2nd ed., XXIV, 1088 Seiten, 135 farbige Abbildungen, 400 Schwarz-Weiß-Abbildungen, Maße: 18,4 x 25,4 cm, Gebunden, Englisch
- Herausgegeben: Gero Decher, Joe B. Schlenoff
- Verlag: Wiley-VCH
- ISBN-10: 3527316485
- ISBN-13: 9783527316489
- Erscheinungsdatum: 13.12.2002
Sprache:
Englisch
Rezension zu „Multilayer Thin Films “
.,."highly recommended to anyone interested in the field...and to scientists and researchers active in materials development..." ("Polymer News") .,."the first book that updates the advances in the multilayer thin-film technology and will remain as the most important book in the field..." ("Pharmaceutical Research," Vol. 20, No. 9, September 2003)
"Each chapter contains pertinent information and discussions completed with a rich and up-to-dated reference; generally, all chapters are well written, the editors and the authors have tried to avoid overlapping of information. ... This multi-authored monograph offers compact and up-to-date information for the beginners, and also for the scientists working in this exciting domain." (Adrian Carpov, "Cellulose Chemistry and Technology," Ed. by the Romanian Academy, January-April, 39/2005)
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