Aryl Diazonium Salts (ePub)
New Coupling Agents in Polymer and Surface Science
(Sprache: Englisch)
Diazonium compounds are employed as a new class of coupling agents to link polymers, biomacromolecules, and other species (e. g. metallic nanoparticles) to the surface of materials. The resulting high performance materials show improved chemical and...
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Diazonium compounds are employed as a new class of coupling agents to link polymers, biomacromolecules, and other species (e. g. metallic nanoparticles) to the surface of materials. The resulting high performance materials show improved chemical and physical properties and find widespread applications. The advantage of aryl diazonium salts compared to other surface modifiers lies in their ease of preparation, rapid (electro)reduction, large choice of reactive functional groups, and strong aryl-surface covalent bonding.
This unique book summarizes the current knowledge of the surface and interface chemistry of aryl diazonium salts. It covers fundamental aspects of diazonium chemistry together with theoretical calculations of surface-molecule bonding, analytical methods used for the characterization of aryl layers, as well as important applications in the field of electrochemistry, nanotechnology, biosensors, polymer coatings and materials science. Furthermore, information on other surface modifiers (amines, silanes, hydrazines, iodonium salts) is included. This collection of 14 self-contained chapters constitutes a valuable book for PhD students, academics and industrial researchers working on this hot topic.
This unique book summarizes the current knowledge of the surface and interface chemistry of aryl diazonium salts. It covers fundamental aspects of diazonium chemistry together with theoretical calculations of surface-molecule bonding, analytical methods used for the characterization of aryl layers, as well as important applications in the field of electrochemistry, nanotechnology, biosensors, polymer coatings and materials science. Furthermore, information on other surface modifiers (amines, silanes, hydrazines, iodonium salts) is included. This collection of 14 self-contained chapters constitutes a valuable book for PhD students, academics and industrial researchers working on this hot topic.
Inhaltsverzeichnis zu „Aryl Diazonium Salts (ePub)“
Preface Attachment of Organic Layers to Materials Surfaces by Reduction of Diazonium Salts Aryl-Surface Bonding: A Density Functional Theory (DFT) Simulation Approach Patterned Molecular Layers on Surfaces Analytical Methods for the Characterization of Aryl Layers Modification of Nano-Objects by Aryl Diazonium Salts Polymer Grafting to Aryl Diazonium-Modified Materials: Methods and Applications Grafting Polymer Films onto Materials Surface: The One-Step Redox Processes Electrografting of Conducting Oligomers and Polymers The Use of Aryl Diazonium Salts in the Fabrication of Biosensors and Chemical Sensors Diazonium Compounds in Molecular Electronics Electronic Properties of Si Surfaces Modified by Aryl Diazonium Compounds Non-Diazonium Organic and Organometallic Coupling Agents for Surface Modification Various Electrochemical Strategies for Grafting Electronic Functional Molecules to Silicon Patents and Industrial Applications of Aryl Diazonium Salts and Other Coupling Agents
Autoren-Porträt
Mohamed M. Chehimi is Research Director at the National Center for Scientific Research (CNRS) in France and the leader of the Surface & Interface research group at ITODYS Laboratory of the University Paris Diderot, where he obtained his PhD in physical organic chemistry in 1988 and finished his Habilitation in 1995. He has authored over 200 scientific publications and has received the Honorary Medal from the Polymer Institute (Slovak Academy of Sciences, Slovakia) for long term and efficient international cooperation on surface and interface aspects of nanocomposites in 2008. His main research interests are aryl diazonium coupling agents, reactive and functional ultrathin polymer films via surface polymerization or "click" chemistry, carbon/polymer composites for the uptake of heavy metals, molecularly imprinted polymer-based sensors, clay/polymer nanocomposites and films, powders, latex particles, and nanocomposites of conductive polypyrrole.
Bibliographische Angaben
- 2012, 1. Auflage, 335 Seiten, Englisch
- Herausgegeben: Mohamed Mehdi Chehimi
- Verlag: Wiley-VCH GmbH
- ISBN-10: 3527650466
- ISBN-13: 9783527650460
- Erscheinungsdatum: 04.06.2012
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- Dateiformat: ePub
- Größe: 8.58 MB
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Sprache:
Englisch
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