Reactions at Solid Surfaces / Baker Lecture Series (PDF)

Preface. 1. Basic principles. 1.1. Introduction: The surface science approach. 1.2. Energetics of chemisorption. 1.3. Kinetics of chemisorption. 1.4. Surface diffusion. References. 2. Surface structure and reactivity. 2.1. Influence of the surface structure on reactivity. 2.2. Growth of two-dimensional phases. 2.3. Electrochemical modification of surface structure. 2.4. Surface reconstruction and transformation. 2.5. Subsurface species and compound formation. 2.6. Epitaxy. References. 3. Dynamics of molecule/surface interactions. 3.1. Introduction. 3.2. Scattering at surfaces. 3.3. Dissociative adsorption. 3.4. Collision-induced surface reactions. 3.5. ''Hot'' adparticles. 3.6. Particles coming off the surface. 3.7. Energy exchange between adsorbate and surface. References. 4. Electronic excitations and surface chemistry. 4.1. Introduction. 4.2. Exoelectron emission. 4.3. Internal electron excitation: ''chemicurrents''. 4.4. Electron-stimulated desorption. 4.5. Surface photochemistry. References. 5. Principles of heterogeneous catalysis. 5.1. Introduction. 5.2. Active sites. 5.3. Langmuir-Hinshelwood versus Eley-Rideal mechanism. 5.4. Coadsorption. 5.5. Kinetics of catalytic reactions. 5.6. Selectivity. References. 6. Mechanisms of heterogeneous catalysis. 6.1. Synthesis of ammonia on iron. 6.2. Synthesis of ammonia on ruthenium. 6.3. Oxidation of carbon monoxide. 6.4. Oxidation of hydrogen on platinum. References. 7. Oscillatory kinetics and nonlinear dynamics. 7.1. Introduction. 7.2. Oscillatory kinetics in the catalytic CO oxidation on Pt(110). 7.3. Forced oscillations in CO oxidation on Pt(110). References. 8. Spatiotemporal self-organization in surface reactions. 8.1. Introduction. 8.2. Turing patterns and electrochemical systems. 8.3. Isothermal wave patterns. 8.4. Modification and control of spatiotemporal patterns. 8.5. Thermokinetic effects. 8.6. Pattern formation on microscopic scale. References. Index.

Gerhard Ertl received his PhD in physical chemistry in 1965 from the Technical University of Munich. He is currently Professor Emeritus at Fritz Haber Institute of the Max Planck Society, Germany, where he was also the Director of the Department of Physical Chemistry from 1986-2004. In addition to winning the 2007 Nobel Prize in Chemistry for his studies of chemical processes on solid surfaces, his many awards received over the years include the Wolf Prize in Chemistry, the Karl Ziegler Prize, the Otto Hahn Prize, and the Japan Prize. He is an acknowledged leader in the field of surface science.

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