Handbook of Transition Metal Polymerization Catalysts (PDF)

Introduction. About the Authors. 1 Commercially Available Metal Alkyls and Their Use in Polyolefin Catalysts (Dennis B. Malpass). 2 Porous Silica in Transition Metal Polymerization Catalysts (Thomas J. Pullukat and Robert E. Patterson). 3 Computational Modeling of Polymerization Catalysts (Monika Srebro and Artur Michalak). 4 Scale-Up of Catalyst Recipes to Commercial Production (C.P. Cheng). 5 Commercialization of Olefin Polymerization Catalysts: Model for Success (C. E. Capshew). 6 Supported Magnesium/Titanium-Based Ziegler Catalysts for Production of Polyethylene (Thomas E. Nowlin, Robert I. Mink, and Yury V. Kissin). 7 Stereospecific alpha-Olefin Polymerization with Heterogeneous Catalysts (John Severn and Robert L. Jones, Jr.). 8 MgCl2-Supported TiCl4 Catalysts for Production of Morphology-Controlled Polyethylene (Long Wu and Sieghard E. Wanke). 9 Product Morphology in Olefin Polymerization with Polymer Supported Metallocene Catalysts (Long Wu and Sieghard E. Wanke). 10 Review of Phillips Chromium Catalyst for Ethylene Polymerization (Max P. McDaniel). 11 Silica-Supported Silyl Chromate-Based Ethylene Polymerization Catalysts (Kevin Cann). 12 Ethylene Polymerization and alpha-Olefin Oligomerization Using Catalysts Derived from Phosphoranes and Ni(II) and Ni(0) Precursors (Scott Collins). 13 Late Transition Metal-Catalyzed Co- and Terpolymerization of alpha-Olefins with Carbon Monoxide-Polyketones: Synthesis and Modification (Timo M. J. Anselment, Manuela Zintl, Maria Leute, Rüdiger Nowack and Bernhard Rieger). 14 Copper Catalysts for Olefin Polymerization (Anna Maria Raspolli Galletti). 15 Ring-Opening Metathesis Polymerizations and Acyclic Diene Metathesis Polymerizations with Homogeneous Ruthenium and Molybdenum Catalysts and Initiators (Robert T. Mathers). 16 Cobalt Ziegler-Natta Catalysts for the Synthesis of Poly-cis-1,4-Butadiene (Ray Hoff). Appendix A Pyrophoricty of Metal Alkyls (Dennis B. Malpass). Appendix B Rheological Terms for Polymerization

Ray Hoff is a member of the adjunct faculty at RooseveltUniversity in Schaumburg, Illinois. He is a former researchscientist in polymerization catalysts for B.F. Goodrich, ChemplexCompany, and Quantum Chemical Corporation. He holds twenty-sevenU.S. patents in the field of polymerization catalysts, and hissilica-based catalyst inventions scaled up to manufacturing morethan 100 million pounds of production in the U.S. and theNetherlands.

Robert T. Mathers is an Assistant Professor of Chemistryat Penn State University. He has coauthored over twenty scientificpapers in the areas of anionic, metallocene, and ring-openingpolymerizations, and holds one U.S. patent. After receiving a BS(1996) in chemistry from North Carolina State University and a PhD(2002) in polymer science from the University of Akron, he spenttwo years as a postdoctoral researcher at Cornell University in theDepartment of Chemistry and Chemical Biology. Currently, Dr.Mathers research investigates new methods to integrate renewableresources and catalysis.

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