Multinuclear Pyrazolate-Based Copper Complexes Inspired by the CuZ-Site of N2O-Reductase (PDF)
(Sprache: Englisch)
Enzymes with multicopper active sites play important roles in many biological processes. Recently a novel multinuclear copper site was discovered in N2O-Reductase and its exact structure and mechanism has been much discussed since then. The so called CuZ...
sofort als Download lieferbar
eBook (pdf)
24.47 €
- Lastschrift, Kreditkarte, Paypal, Rechnung
- Kostenloser tolino webreader
Produktdetails
Produktinformationen zu „Multinuclear Pyrazolate-Based Copper Complexes Inspired by the CuZ-Site of N2O-Reductase (PDF)“
Enzymes with multicopper active sites play important roles in many biological processes. Recently a novel multinuclear copper site was discovered in N2O-Reductase and its exact structure and mechanism has been much discussed since then. The so called CuZ center contains a unique tetranuclear Cu4S2-Cluster, which is coordinated by seven histidine residues. Until now no synthetic model complex could be isolated that emulates the Cu4S2 core of the active site.
In this thesis a new strategy towards such model systems is introduced. To mimic the nitrogen-rich environment of the copper ions, pyrazolate-based ligand scaffolds with chelating N-donor side arms are employed. The resulting binuclear metal complexes were isolated and fully characterized. Additionally the reactivity of these binuclear building blocks towards various sulfur-containing coligands and sulfur-transfer reagents was investigated.
In this thesis a new strategy towards such model systems is introduced. To mimic the nitrogen-rich environment of the copper ions, pyrazolate-based ligand scaffolds with chelating N-donor side arms are employed. The resulting binuclear metal complexes were isolated and fully characterized. Additionally the reactivity of these binuclear building blocks towards various sulfur-containing coligands and sulfur-transfer reagents was investigated.
Bibliographische Angaben
- 2011, 205 Seiten, Englisch
- Verlag: Cuvillier Verlag
- ISBN-10: 3736939787
- ISBN-13: 9783736939783
- Erscheinungsdatum: 22.12.2011
Abhängig von Bildschirmgröße und eingestellter Schriftgröße kann die Seitenzahl auf Ihrem Lesegerät variieren.
eBook Informationen
- Dateiformat: PDF
- Größe: 4.91 MB
- Ohne Kopierschutz
- Vorlesefunktion
Sprache:
Englisch
Family Sharing
eBooks und Audiobooks (Hörbuch-Downloads) mit der Familie teilen und gemeinsam genießen. Mehr Infos hier.
Kommentar zu "Multinuclear Pyrazolate-Based Copper Complexes Inspired by the CuZ-Site of N2O-Reductase"
0 Gebrauchte Artikel zu „Multinuclear Pyrazolate-Based Copper Complexes Inspired by the CuZ-Site of N2O-Reductase“
Zustand | Preis | Porto | Zahlung | Verkäufer | Rating |
---|
Schreiben Sie einen Kommentar zu "Multinuclear Pyrazolate-Based Copper Complexes Inspired by the CuZ-Site of N2O-Reductase".
Kommentar verfassen