Principles of Polymerization (PDF)

Preface. 1. Introduction. 1.1 Types of Polymers and Polymerizations. 1.2 Nomenclature of Polymers. 1.3 Linear, Branched, and Crosslinked Polymers. 1.4 Molecular Weight. 1.5 Physical State. 1.6 Applications of Polymers. 2. Step Polymerization. 2.1 Reactivity of Functional Groups. 2.2 Kinetics of Step Polymerization. 2.3 Accessibility of Functional Groups. 2.4 Equilibrium Considerations. 2.5 Cyclization versus Linear Polymerization. 2.6 Molecular Weight Control in Linear Polymerization. 2.7 Molecular Weight Distribution in Linear Polymerization. 2.8 Process Condition. 2.9 Multichain Polymerization. 2.10 Crosslinking. 2.11 Molecular Weight Distributions in Nonlinear Polymerizations. 2.12 Crosslinking Technology. 2.13 Step Copolymerization. 2.14 High-Performance Polymers. 2.15 Inorganic and Organometallic Polymers. 2.16 Dendric (Highly Branched) Polymers. 3. Radical Chain Polymerization. 3.1 Nature and Radical Chain Polymerization. 3.2 Structural Arrangement of Monomer Units. 3.3 Rate of Radical Chain Polymerization. 3.4 Initiation. 3.5 Molecular Weight. 3.6 Chain Transfer. 3.7 Inhibition and Retardation. 3.8 Determination of Absolute Rate Constants. 3.9 Energetic Characteristics. 3.10 Autoacceleration. 3.11 Molecular Weight Distribution. 3.12 Effect of Pressure. 3.13 Process Conditions. 3.14 Specific Commercial Polymers. 3.15 Living Radical Polymerization. 3.16 Other Polymerizations. 4. Emulsion Polymerization. 4.1 Description of Process. 4.2 Quantitative Aspects. 4.3 Other Characteristics of Emulsion Polymerization. 5. Ionic Chain Polymerization. 5.1 Comparison of Radical and Ionic Polymerization. 5.2 Cationic Polymerization of the Carbon-Carbon Double Bond. 5.3 Anionic Polymerization of the Carbon-Carbon Double. 5.4 Block and Other Polymer Architecture. 5.5 Distinguishing Between Radical, Cationic, and Anionic Polymerizations. 5.6 Carbonyl Polymerization. 5.7 Miscellaneous Polymerizations. 6. Chain Copolymerization. 6.1 General Considerations. 6.2 Copolymer

GEORGE ODIAN received his PhD from Columbia University. He is currently Emeritus Professor of Chemistry at the College of Staten Island of the City University of New York. He has previously served as professor of chemistry and chairman, Division of Pure and Applied Sciences at Richmond College of CUNY, assistant professor at Columbia University, research director of RAI Research Company, and research chemist at Thiokol Chemical Company. He has written over sixty research publications and authored both taped and short courses for the American Chemical Society. He is also the coauthor of four books in general, organic, and biochemistry.

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