Solid State Polymerization (PDF)

Contributors. Preface. 1 Fundamentals of Solid State Polymerization (C. D. Papaspyrides and S. N. Vouyiouka). 1.1 Introduction. 1.2 Solid State Polymerization of Chain-Growth Polymers (Solid State Polyaddition). 1.3 Solid State Polymerization of Step-Growth Polymers (Solid State Polycondensation). 1.4 Solid State Polymerization Apparatus and Assemblies. 1.5 Solid State Applications in the Polymer Industry. 1.6 Conclusions. 2 Solid State Polymerization Chemistry and Mechanisms: Unequal Reactivity of End Groups (Haibing Zhang and Saleh A. Jabarin). 2.1 Introduction. 2.2 Special Characteristics of Solid State Polymerization. 2.3 Classical Kinetic Equations in Solid State Polymerization. 2.4 Model of Molecular Morphology and Chain-End Movement. 2.5 Reactivity of End Groups. 2.6 Why Intrinsic Viscosity Levels Off During Solid State Polymerization. 2.7 Solid State Polymerization Kinetics. 2.8 Conclusions. 3 Kinetic Aspects of Polyester Solid State Polymerization (F. Pilati and M. Toselli). 3.1 Introduction. 3.2 Phenomena Involved in Solid State Polymerization of Polyesters. 3.3 Modeling Solid State Polymerization of Polyesters. 3.4 Solid State Polymerization of Typical Polyesters. 3.5 Conclusions. 4 Kinetic Aspects of Polyamide Solid State Polymerization (S. N. Vouyiouka and C. D. Papaspyrides). 4.1 Introduction. 4.2 Simple Kinetic Models of Solid State Polyamidation. 4.3 Simulation of Solid State Polyamidation. 4.4 Simple SSP Kinetics: The Case of Poly(hexamethylene adipamide). 4.5 Conclusions. 5 Catalysis in Solid State Polymerization Processes (Rudolf Pfaendner). 5.1 Introduction. 5.2 Catalysts in Polyester Solid State Polymerization Processes. 5.3 Catalysts in Polyamide Solid State Polymerization Processes. 5.4 Reactive Additives in Solid State Polymerization Processes. 5.5 Inert Additives in Solid State Polymerization Processes. 5.6 Conclusions. 6 High-Pressure Solid State Polymerization of Polyamide Monomer Crystals (Tokimitsu Ikawa). 6.1 Introduction. 6.2

Constantine D. Papaspyrides is Professor and Director of the
Laboratory of Polymer Technology in the School of Chemical
Engineering at the National Technical University of Athens, Greece.
He has been ex-President of the School and Visiting
Professor/Consultant in Massachusetts Institute of Technology
(MIT), Eidgenssische Technische Hochschule Zrich (ETH), E.I. du
Pont de Nemours & Company, Inc. / Invista, Inc., and Ciba
Lampertheim GmbH. He serves on the editorial board for the journals
Advances in Polymer Technology Journal (Wiley) and Progress in
Rubber, Plastics and Recycling Technology Journal (Rapra
Technology).

Stamatina N. Vouyiouka is elected Lecturer in the School of
Chemical Engineering at the National Technical University of Athens
in Greece.

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