Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes (PDF)
(Sprache: Englisch)
The phosphinoamide chemistry has attracted a considerable attention owing to the structural
diversity of the associated complexes.[16-21] To further understand the properties of the P-N bond,
Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)]2...
diversity of the associated complexes.[16-21] To further understand the properties of the P-N bond,
Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)]2...
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The phosphinoamide chemistry has attracted a considerable attention owing to the structural
diversity of the associated complexes.[16-21] To further understand the properties of the P-N bond,
Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)]2 (Figure 1.1.1) through the
deprotonation reaction of the corresponding aminophosphine with nBuLi.[22] X-ray diffraction
analyses indicated the presence of Li-P bonds (2.684(3) and 3.004(4) Å). In addition, the P-N
bond length (1.672(2) Å) was relatively smaller than that of a single bond (mean value of 1.70
diversity of the associated complexes.[16-21] To further understand the properties of the P-N bond,
Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)]2 (Figure 1.1.1) through the
deprotonation reaction of the corresponding aminophosphine with nBuLi.[22] X-ray diffraction
analyses indicated the presence of Li-P bonds (2.684(3) and 3.004(4) Å). In addition, the P-N
bond length (1.672(2) Å) was relatively smaller than that of a single bond (mean value of 1.70
Bibliographische Angaben
- 2019, 138 Seiten, Englisch
- Verlag: Cuvillier Verlag
- ISBN-10: 3736960344
- ISBN-13: 9783736960343
- Erscheinungsdatum: 20.06.2019
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Englisch
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