Bridging Heterogeneous and Homogeneous Catalysis
Concepts, Strategies, and Applications
(Sprache: Englisch)
This unique handbook fills the gap in the market for an up-to-date work that links both homogeneous catalysis applied to organic reactions and catalytic reactions on surfaces of heterogeneous catalysts.
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Klappentext zu „Bridging Heterogeneous and Homogeneous Catalysis “
This unique handbook fills the gap in the market for an up-to-date work that links both homogeneous catalysis applied to organic reactions and catalytic reactions on surfaces of heterogeneous catalysts.
Inhaltsverzeichnis zu „Bridging Heterogeneous and Homogeneous Catalysis “
PrefaceACID-BASE COOPERATIVE CATALYSIS FOR ORGANIC REACTIONS BY DESIGNED SOLID SURFACES WITH ORGANOFUNCTIONAL GROUPSIntroductionBifunctional Catalysts Possessing both Acidic and Basic Organic GroupsBifunctional Catalysts Possessing Basid Organic Groups and Acid Sites Derived from their Support SurfaceProspectCATALYTIC REACTIONS IN OR BY ROOM TEMPERATURE IONIC LIQUIDS: BRIDGING THE GAP BETWEEN HOMOGENEOUS AND HETEROGENEOUS CATALYSISIntroduction and BackgroundCatalysis with IL-Supported or Mediated Metal NanoparticlesReactions Catalyzed by Solids Support IL: Heterogeneous Catalysis with Homogeneous PerformanceOutlookHETEROGENEOUS CATALYSIS WITH ORGANI-INORGANIC HYBRID MATERIALSIntroductionOrganic-Inorganic Hybrid MaterialsCatalytic Applications of Organic-Inorganic Hybrid MaterialsConclusionHOMOGENEOUS ASYMMETRIC CATALYSIS USING IMMOBILIZED CHIRAL CATALYSTSIntroductionSoluble Polymeric Supports and Catalyst Separation MethodsChiral Linear Polymeric CatalystsChiral Dendritic CatalystsHelical Polymeric CatalystsConclusion and ProspectENDEAVORS TO BRIDGE THE GAP BETWEEN HOMO- & HETEROGENEOUS ASYMMETRIC CATALYSIS WITH ORGANOMETALLICSGeneral IntroductionCombinatorial Approach for Homogeneous Asymmetric CatalysisSelf-Supporting Approach for Heterogeneous Asymmetric CatalysisConclusions and OutlookCATALYSIS IN AND ON WATERIntroductionCatalytic Reactions in and "on" WaterConclusionA GREEN CHEMISTRY STRATEGY: FLUOROUS CATALYSISHistory of Fluorous ChemistryBasics of Fluorous ChemistryFluorous Metallic CatalysisFluorous OrganocatalysisConclusionEMULSION CATALYSIS: INTERFACE BETWEEN HOMOGENEOUS AND HETEROGENEOUS CATALYSISIntroductionEmulsion Catalysis in the Oxidative DesulfurizationEmulsion Catalysis in the Lewis Acid-Catalyzed Organic ReactionEmulsion Catalysis in Reactions with OrganocatalystsEmulsion Formed with Polymer Bounded CatalystsConclusion and PerspectiveIDENTIFICATION OF BINDING AND REACTIVE SITES IN METAL CLUSTER CATALYSIS: HOMOGENEOUS-HETEROGENEOUS
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BRIDGESIntroductionControl of Binding in Metal-Carbonyl Clusters via Ligand EffectsImaging of CO Binding on Nobel Metal ClustersImaging of Open Sites in Metal Cluster CatalysisElucidating Kinetic Contributions of Open Sites: Kinetic Poisoning Experiments Using Organic LigandsMore Approaches to Poisoning Open Catalytic Active Sites to Obtain Structure Function RelationshipsSupported Molecular Iridium Clusters for Ethylene HydrogenationSummary and OutlookCATALYSIS IN POROUS-MATERIAL-BASED NANOREACTORS: A BRIDGE BETWEEN HOMOGENEOUS AND HETEROGENEOUS CATALYSISIntroductionPreparation of Nanoreactors Based on Porous MaterialsAssembly of the Molecular Catalysts in NanoreactorCatalytic Reactions in NanoreactorConclusions and PerspectivesHETEROGENEOUS CATALYSIS BY GOLD CLUSTERSIntroductionPreparation of Gold ClustersCharacterization of Gold ClustersCatalysis by Gold ClustersConclusions and PerspectivesASYMMETRIC PHASE-TRANSFER CATALYSIS IN ORGANIC SYNTHESISIntroductionChiral Phase-Transfer CatalystsAsymmetric Phase-Transfer Catalytic Reactions and ApplicationsConcluding RemarksCATALYSIS IN SUPERCRITICAL FLUIDSIntroductionFeatures of Supercritical Fluids and Related Catalytic ReactionsExamples of the Reactions in SCFsSummary and ConclusionsHYDROFORMYLATION OF OLEFINS IN AQUEOUS-ORGANIC BIPHASIC CATALYTIC SYSTEMSIntroductionWater-Soluble Rhodium Phosphin Complex Catalytic SystemsMechanismHydroformylation of Lower OlefinsHydroformulation of Higher OlefinHydroformulation of Internal OlefinsConclusion and OutlookRECENT PROGRESS IN ENZYME CATALYSIS IN REVERSE MICELLESIntroductionEnzyme Catalysis in Molecular Organic Solvent-Based Reverse MicellesEnzyme Catalysis in Ionic Liquid-Based Reverse MicellesApplications of Enzyme Catalysis in Reverse MicellesConcluding RemarksTHE MOLECULAR KINETICS OF THE FISCHER-TROPSCH REACTIONIntroductionBasics of FT KineticsMolecular Microkinetics SimulationsThe Lumped Microkinetics ModelTransient Kinetics SimulationsConclusion and Summary
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Autoren-Porträt
Can Li received his PhD degree from the Dalian Institute of Chemical Physics (China) in 1988, was promoted to full professor in 1993, and was elected as a member of the Chinese Academy of Sciences in 2003. He was appointed director of the State Key Laboratory of Catalysis at the Dalian Institute of Chemical Physics in 1998 and elected to the President of the International Association of Catalysis Societies in 2008. He is a member of the editorial board of more than 15 academic journals and has published more than 400 peer-reviewed papers, authorized 40 patents and delivered more than 60 invited and plenary lectures at national and international conferences. Under his supervision, more than 60 graduate students have obtained their PhD degrees. Among the prestigious awards he received are the International Catalysis Award, the National Award for Outstanding Young Scientists in China, and the HoLeungHoLee Prize. His research interests are physical chemistry, catalysis, environmental catalysis, chiral catalysis, in-situ characterization, resonance and time-resolved spectroscopy, and solar energy utilization (photocatalysis, photoelectrocatalysis and photovoltaic).Yan Liu studied chemistry at Lanzhou University (China) and then moved to the State Key Laboratory of Organometallic Chemistry at the Shanghai Institute of Organic Chemistry to obtain his PhD degree under the supervision of Prof. Kuiling Ding in 2006. After three years of postdoctoral studies with Prof. Li Deng, Brandeis University (USA), he joined Prof. Can Li?s group at the State Key Laboratory of Catalysis at the Dalian Institute of Chemical Physics in 2010 as associate professor and was promoted to full professor in 2013.
Bibliographische Angaben
- 2014, 656 Seiten, 20 farbige Abbildungen, 180 Schwarz-Weiß-Abbildungen, Maße: 17,2 x 25,1 cm, Gebunden, Englisch
- Herausgegeben: Can Li, Yan Liu
- Verlag: Wiley-VCH
- ISBN-10: 3527335838
- ISBN-13: 9783527335831
- Erscheinungsdatum: 29.04.2014
Sprache:
Englisch
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