Fortschritte der Chemie organischer Naturstoffe / Progress in the Chemistry of Organic Natural Products
(Sprache: Englisch)
Naturally Occurring 6-substituted 5,6-dihydro-?-pyrones.- 1. Introduction.- 2. Nomenclature and Classification.- 3. Distribution and Structure Determination.- 3.1. 6-Alkyl-5,6-dihydro-?-pyrones.- 3.2. 6-Alkenyl-5,6-dihydro-?-pyrones.- 3.3....
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Klappentext zu „Fortschritte der Chemie organischer Naturstoffe / Progress in the Chemistry of Organic Natural Products “
Naturally Occurring 6-substituted 5,6-dihydro-?-pyrones.- 1. Introduction.- 2. Nomenclature and Classification.- 3. Distribution and Structure Determination.- 3.1. 6-Alkyl-5,6-dihydro-?-pyrones.- 3.2. 6-Alkenyl-5,6-dihydro-?-pyrones.- 3.3. 6-Aryl-5,6-dihydro-?-pyrones.- 4. Physical Methods of Structure Determination.- 4.1. 1H- and 13C-NMR Spectroscopy.- 4.2. Mass Spectrometry.- 4.3. Infrared and Ultraviolet Spectroscopy.- 4.4. Circular Dichroism.- 5. Biosynthesis.- 6. Biological Activity.- References.- Addendum.- Building Blocks for the Total Synthesis of Anthracyclinones.- I. Introduction.- II. General Synthetic Methods.- 1. Friedel-Crafts Reactions.- 2. Diels-Alder Reactions.- 3. Anionic Reactions.- 4. Transition Metal Mediated Reactions.- III. Synthesis of Building Blocks for Rings A and B.- IV. Construction of Ring A.- 1. Diels-Alder Reactions.- 2. Electrophilic Additions.- 3. Nucleophilic Additions.- V. Building Blocks for Rings C and D.- VI. Concluding Remarks.- References.- Indole Alkaloid Production in Catharanthus roseus Cell Suspension Cultures.- 1. Introduction.- 2. Discussion.- 2.1. Indole Alkaloids and Their Formation in the Plant and in Cell Cultures.- 2.2. General Methods of Catharanthus roseus Cell Suspension Culture Work.- 2.2.1. Analytical Methods.- 2.2.2. Development of High Yielding Cell Lines.- 2.2.3. Growth and Alkaloid Production in Catharanthus roseus Cell Suspension Cultures.- 2.2.4. Effects of Culture Conditions on Growth and Alkaloid Production..- 2.2.4.1. Medium Composition.- 2.2.4.2. Addition of Precursors.- 2.2.4.3. Light.- 2.2.4.4. Temperature.- 2.2.4.5. Gaseous Environment.- 2.2.5. One-stage Systems.- 2.2.6. Large-scale Fermentation.- 2.2.7. Immobilized Cell Systems.- 2.2.8. Cell Free Systems.- 3. Conclusions.- References.- Sucrose and Its Derivatives.- 1. Introduction.- 1.1. History.- 1.2. Structure.- 1.3. Nomenclature.- 1.4. Synthesis.- 1.5. Biosynthesis.- 1.6. Conformation.- 2. Protective and Functional Groups.- 2.1. Ethers.-
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2.1.1. Tritylation.- 2.1.2. Methylation.- 2.1.3. Silylation.- 2.2. Cyclic Acetals.- 2.3. Esters.- 2.3.1. Carboxylates.- 2.3.1.1. Acetates.- 2.3.1.2. Benzoates.- 2.3.1.3. Benzoylpropionates.- 2.3.1.4. Pivalates.- 2.3.2. Sulphonates.- 2.3.3. Chlorosulphates.- 2.3.4. Other Esters.- 3. Derivatives.- 3.1. Anhydrides (Oxetanes) and Epoxides (Oxiranes).- 3.2. Halides.- 3.3. Unsaturated, Deoxy and Branched-Chain Compounds.- 3.4. Nitrogen-containing Compounds: Azides, Amines and Morpholines.- 3.5. Sulphur Derivatives.- 4. Enhancement of Sweetness: Structure Activity Relationships.- 5. Natural Products Containing Sucrose.- 5.1. ?-D-Fructofuranosyl Derivatives.- 5.2. ?-D-Glucopyranosyl Derivatives.- 5.3. ?-and ?-D-Galactopyranosyl Derivatives.- 5.4. Galloyl Derivatives.- 5.5 Agricinopine A.- 5.6. Sucrose Esters from Potato.- 5.7. Sucrose Esters from Tobacco.- Acknowledgment.- References.- Author Index.
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Inhaltsverzeichnis zu „Fortschritte der Chemie organischer Naturstoffe / Progress in the Chemistry of Organic Natural Products “
- Naturally Occurring 6-substituted 5,6-dihydro-?-pyrones1. Introduction
2. Nomenclature and Classification
3. Distribution and Structure Determination
3.1. 6-Alkyl-5,6-dihydro-?-pyrones
3.2. 6-Alkenyl-5,6-dihydro-?-pyrones
3.3. 6-Aryl-5,6-dihydro-?-pyrones
4. Physical Methods of Structure Determination
4.1. 1H- and 13C-NMR Spectroscopy
4.2. Mass Spectrometry
4.3. Infrared and Ultraviolet Spectroscopy
4.4. Circular Dichroism
5. Biosynthesis
6. Biological Activity
- References
- Addendum
- Building Blocks for the Total Synthesis of Anthracyclinones
I. Introduction
II. General Synthetic Methods
1. Friedel-Crafts Reactions
2. Diels-Alder Reactions
3. Anionic Reactions
4. Transition Metal Mediated Reactions
III. Synthesis of Building Blocks for Rings A and B
IV. Construction of Ring A
1. Diels-Alder Reactions
2. Electrophilic Additions
3. Nucleophilic Additions
V. Building Blocks for Rings C and D
VI. Concluding Remarks
- References
- Indole Alkaloid Production in Catharanthus roseus Cell Suspension Cultures
1. Introduction
2. Discussion
2.1. Indole Alkaloids and Their Formation in the Plant and in Cell Cultures
2.2. General Methods of Catharanthus roseus Cell Suspension Culture Work
2.2.1. Analytical Methods
2.2.2. Development of High Yielding Cell Lines
2.2.3. Growth and Alkaloid Production in Catharanthus roseus Cell Suspension Cultures
2.2.4. Effects of Culture Conditions on Growth and Alkaloid Production
2.2.4.1. Medium Composition
2.2.4.2. Addition of Precursors
2.2.4.3. Light
2.2.4.4. Temperature
2.2.4.5. Gaseous Environment
2.2.5. One-stage Systems
2.2.6. Large-scale Fermentation
2.2.7. Immobilized Cell Systems
2.2.8. Cell Free Systems
3. Conclusions
- References
- Sucrose and Its Derivatives
1. Introduction
1.1. History
1.2. Structure
1.3. Nomenclature
1.4. Synthesis
1.5. Biosynthesis
1.6. Conformation
2. Protective and Functional Groups
2.1. Ethers
2.1.1. Tritylation
2.1.2. Methylation
2.1.3.
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Silylation
2.2. Cyclic Acetals
2.3. Esters
2.3.1. Carboxylates
2.3.1.1. Acetates
2.3.1.2. Benzoates
2.3.1.3. Benzoylpropionates
2.3.1.4. Pivalates
2.3.2. Sulphonates
2.3.3. Chlorosulphates
2.3.4. Other Esters
3. Derivatives
3.1. Anhydrides (Oxetanes) and Epoxides (Oxiranes)
3.2. Halides
3.3. Unsaturated, Deoxy and Branched-Chain Compounds
3.4. Nitrogen-containing Compounds: Azides, Amines and Morpholines
3.5. Sulphur Derivatives
4. Enhancement of Sweetness: Structure Activity Relationships
5. Natural Products Containing Sucrose
5.1. ?-D-Fructofuranosyl Derivatives
5.2. ?-D-Glucopyranosyl Derivatives
5.3. ?-and ?-D-Galactopyranosyl Derivatives
5.4. Galloyl Derivatives
5.5 Agricinopine A
5.6. Sucrose Esters from Potato
5.7. Sucrose Esters from Tobacco
- Acknowledgment
- References
- Author Index
2.2. Cyclic Acetals
2.3. Esters
2.3.1. Carboxylates
2.3.1.1. Acetates
2.3.1.2. Benzoates
2.3.1.3. Benzoylpropionates
2.3.1.4. Pivalates
2.3.2. Sulphonates
2.3.3. Chlorosulphates
2.3.4. Other Esters
3. Derivatives
3.1. Anhydrides (Oxetanes) and Epoxides (Oxiranes)
3.2. Halides
3.3. Unsaturated, Deoxy and Branched-Chain Compounds
3.4. Nitrogen-containing Compounds: Azides, Amines and Morpholines
3.5. Sulphur Derivatives
4. Enhancement of Sweetness: Structure Activity Relationships
5. Natural Products Containing Sucrose
5.1. ?-D-Fructofuranosyl Derivatives
5.2. ?-D-Glucopyranosyl Derivatives
5.3. ?-and ?-D-Galactopyranosyl Derivatives
5.4. Galloyl Derivatives
5.5 Agricinopine A
5.6. Sucrose Esters from Potato
5.7. Sucrose Esters from Tobacco
- Acknowledgment
- References
- Author Index
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Bibliographische Angaben
- Autoren: M. T. Davies-Coleman , J. Galambos , L. Hough , C. E. James , R. Khan , K. Krohn , M. Lounasmaa , D. E. A. Rivett
- 2012, Softcover reprint of the original 1st ed. 1989, X, 208 Seiten, 41 Abbildungen, Maße: 15,2 x 22,9 cm, Kartoniert (TB), Englisch
- Herausgegeben: W. Herz, H. Grisebach, G. W. Kirby, Ch. Tamm
- Verlag: Springer
- ISBN-10: 3709190045
- ISBN-13: 9783709190043
- Erscheinungsdatum: 05.01.2012
Sprache:
Englisch
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