Functional Metal Oxides
New Science and Novel Applications
(Sprache: Englisch)
Functional oxides are used both as insulators and metallic conductors in key applications across all industrial sectors. This makes them attractive candidates in modern technology ? they make solar cells cheaper, computers more efficient and medical instrumentation more sensitive.
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Functional oxides are used both as insulators and metallic conductors in key applications across all industrial sectors. This makes them attractive candidates in modern technology ? they make solar cells cheaper, computers more efficient and medical instrumentation more sensitive.
Klappentext zu „Functional Metal Oxides “
Functional oxides are used both as insulators and metallic conductors in key applications across all industrial sectors. This makes them attractive candidates in modern technology ? they make solar cells cheaper, computers more efficient and medical instrumentation more sensitive. Based on recent research, experts in the field describe novel materials, their properties and applications for energy systems, semiconductors, electronics, catalysts and thin films.This monograph is divided into 6 parts which allows the reader to find their topic of interest quickly and efficiently.* Magnetic Oxides * Dopants, Defects and Ferromagnetism in Metal Oxides * Ferroelectrics * Multiferroics * Interfaces and Magnetism * Devices and ApplicationsThis book is a valuable asset to materials scientists, solid state chemists, solid state physicists, as well as engineers in the electric and automotive industries.
Inhaltsverzeichnis zu „Functional Metal Oxides “
PREFACE PART I: Magnetic Oxides INTRODUCTION TO MAGNETIC OXIDES Oxide Structures and Crystal Chemistry Oxide GrowthMagnetic Properties of 3d and 4f Ions Magnetic Interactions in Oxides Concentrated Magnetic OxidesDilute Magnetic Oxides Conclusions MAGNETIC/MULTIFUNCTIONAL DOUBLE PEROVSKITE OXIDE THIN FILMS Introduction Thin-Film Deposition Structure and Morphology Electronic Structure Physical Properties Applications of Multifunctional Oxides Future DirectionsPART II: Dopants, Defects and Ferromagnetism in Metal Oxides MAGNETIC OXIDE SEMICONDUCTORS: ON THE HIGH-TEMPERATURE FERROMAGNETISM IN TIO2- AND ZNO-BASED COMPOUNDS IntroductionProperties of (Ti,Co)O2Properties of Transition-Metal-Doped ZnO Discussion Summary and OutlooksEFFECT OF TA ALLOYING ON THE OPTICAL, ELECTRONIC, AND MAGNETIC PROPERTIES OF TIO2 THIN FILMS Introduction Ta Substitution in TiO2: Doping or Alloying? Diluted Magnetic Semiconductors (DMS) Defect-Mediated Ferromagnetism Magnetic Impurity Analysis in Ti1-xTaxO2 System Defect-Induced Ferromagnetism in Ti1-xTaxO2 Film First-Principles Spin-Polarized GGA + U Calculations Mechanism of Defect-Mediated FM Optimization of FerromagnetismOutlook for Defect-Mediated Properties of Ti1-xTaxO2 DEFECT-INDUCED OPTICAL AND MAGNETIC PROPERTIES OF COLLOIDAL TRANSPARENT CONDUCTING OXIDE NANOCRYSTALS Introduction Colloidal Transition-Metal-Doped Transparent Conducting Oxide Nanocrystals Native Defects in Colloidal Transparent Conducting Oxide NanocrystalsSummary and Outlook PART III: Ferroelectrics STRUCTURE - PROPERTY CORRELATIONS IN RARE-EARTH-SUBSTITUTED BIFEO3 EPITAXIAL THIN FILMS AT THE MORPHOTROPIC PHASE BOUNDARY Introduction Combinatorial Discovery of a MPB in Sm-substituted BiFeO3 (Sm-BFO) Structural Evolution across the MPB in Sm-BFO Universal Behavior in RE-Substituted BFO Structural Fingerprint of MPB in RE-Substituted BFO Chemical-Substitution-Induced Polarization Rotation in BFO Concluding Remarks and Future Perspectives ANTIFERROELECTRICITY IN OXIDES:
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A REEXAMINATION Introduction Definition and Characteristic PropertiesMicroscopic Origins of Macroscopic BehaviorAntiferroelectric Materials: Structure and Properties Relation to Alternative Ferroelectric Phases Antiferroelectricity in Thin Films Properties for ApplicationsProspects PART IV: Multiferroics PROBING NANOSCALE ELECTRONIC CONDUCTION IN COMPLEX OXIDES Scanning-Probe-Based Transport Measurements Domain Wall Conductivity Photovoltaic Effects at Domain WallsLocal Characterization of Doped Oxides and Defects Local Electronic Probing of Oxide Interfaces Nanoscale Electronic Properties of CMR Manganites Future Directions MULTIFERROICS WITH MAGNETOELECTRIC COUPLING Introduction: Ferroic Materials Principles of Symmetry Analysis Magnetoelectric Couplings and a Landau-Like Theory Chemical Considerations Classification of Multiferroics Multiferroic Materials and Mechanisms Microscopic Mechanisms of Magnetic Ferroelectricity: Type II Multiferroics Domains and Metal - Insulator TransitionPART V: Interfaces and Magnetism DEVICE ASPECTS OF THE SRTIO3 - LAALO3 INTERFACE; BASIC PROPERTIES, MOBILITY, NANOSTRUCTURING, AND POTENTIAL APPLICATIONS Introduction The LaAlO3/SrTiO3 Interface: Key Characteristics and Understanding Charge-Carrier Mobility Micro/Nanostructuring Electric Field Gating Applications X-RAY SPECTROSCOPIC STUDIES OF CONDUCTING INTERFACES BETWEEN TWO INSULATING OXIDES Introduction Photoemission Measurements of Interfaces Interfaces between a Mott Insulator and a Band Insulator: LaAlO3/LaVO3 and LaTiO3/SrTiO3 Interfaces between Two Band Insulators: LaAlO3/SrTiO3 Summary INTERFACIAL COUPLING BETWEEN OXIDE SUPERCONDUCTORS AND FERROMAGNETSIntroduction Experimental Results Materials Considerations Conclusions PART VI: Devices and Applications METAL-OXIDE NANOPARTICLES FOR DYE-SENSITIZED SOLAR CELLS TiO2: Polymorphism, Optoelectronic Properties, and Bandgap Engineering Principle and Basis of Dye-Sensitized Solar Cell (DSC) Technology Progress in TiO2 Engineering for Improved Charge-Collection Efficiency and Light Confinement Development of Molecular Sensitizers Suited to TiO2 Optoelectronic Properties Development of Redox Mediators Conclusions HYBRID SOLAR CELLS FROM ORDERED NANOSTRUCTURES Introduction Working Mechanisms of Hybrid Solar Cells Nanostructures for Hybrid Solar CellsMetal Oxide Modifications Conclusion and Outlook ELECTRIC FIELD EFFECTS IN FUNCTIONAL METAL OXIDES Introduction Developments of Gate Dielectrics: from High-k Oxides to Ionic Electrolytes Electric-Field-Induced Modulation of Ferromagnetism Electrostatic Modulation of Superconductivity Transparent Amorphous Metal-Oxide Field-Effect Transistors Solution-Processable Transparent Amorphous Metal Oxides for Thin-Film TransistorsChallenges and OpportunitiesRESISTIVE SWITCHINGS IN TRANSITION-METAL OXIDES Introduction Classification of Current - Voltage Hystereses Bipolar Continuous Switching Toward Device Applications and Summary INDEX
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Autoren-Porträt
Satishchandra Ogale is a Chief Scientist and Coordinator of the Centre of Excellence in Solar Energy at the National Chemistry Laboratory (CSIR-NCL) in Pune (India), and a Professor of Physical Sciences at the AcSIR, CSIR, New Delhi. After obtaining his academic degrees from the University of Poona, he spent nine years as Senior Researcher at the University of Maryland, College Park, (USA). Dr. Ogale has authored more than 370 research publications and one book. His current interest is in the fi eld of nanostructured metal oxides for energy applications.Venky Venkatesan had a 17 year stint at Bell Labs and Bellcore before moving to the University of Maryland. While at Bell he was the founding Director of the Surface Modification and Interface Dynamics Laboratory at Rutgers University. After the canonical 17 years he moved to the National University of Singapore to establish a Nano Institute there, NUSNNI-NanoCore. He is known for the invention of the PLD process and has over 500 publications in the area of oxide thin films, heterostructures and interfaces. He is among the top 100 most cited Physicists, Fellow of the American Physical Society, winner of the Bellcore Award of Excellence, and the George E Pake Prize of the APS in 2012. He isthe founder and Chairman of Neocera, a company specializing in pulsed energy deposition systems and magnetic imaging systems for semiconductor device analysis.Mark Blamire is Professor of Device Materials and Head of the Materials Science Department at the University of Cambridge (UK). He has studied and worked at the University of Cambridge since he was an undergraduate. Prof. Blamire has authored more than 400 research publications and is a Fellow of the Institute of Physics. His research is based on the study of novel materials or new materials combinations for potential device applications. These materials include metals, oxides, nitrides with properties such as superconductivity, magnetism and ferroelectricity.
Bibliographische Angaben
- 2013, 498 Seiten, Maße: 17,7 x 24,9 cm, Gebunden, Englisch
- Herausgegeben: Satishchandra B. Ogale, T. Venky Venkatesan, Mark Blamire
- Verlag: Wiley-VCH
- ISBN-10: 3527331794
- ISBN-13: 9783527331796
- Erscheinungsdatum: 12.09.2013
Sprache:
Englisch
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