N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis
(Sprache: Englisch)
N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis features all catalytic reactions enabled by N-heterocyclic carbenes (NHCs), either directly as organocatalysts or as ligands for transition metal catalysts. An explosion in the use...
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N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis features all catalytic reactions enabled by N-heterocyclic carbenes (NHCs), either directly as organocatalysts or as ligands for transition metal catalysts. An explosion in the use of NHCs has been reported in the literature during the past seven years making this comprehensive overview highly apropos.
The book begins with an introductory overview of NHCs which could have been subtitled all you need to know about NHCs. The main body of the book is dedicated to applications of NHCs in catalysis. In addition to the success stories of NHCs in metathesis, NHCs in cross coupling and more recently NHCs in organocatalysis, all other less publicized areas are also covered. As the success of NHCs is generally attributed to their potential to stabilize metal centres, the inclusion of a chapter on the decomposition of NHC catalysts is pertinent. The book closes with a chapter describing the applications of NHCs in industrial processes, which is the first coverage of its kind, and brings a unique industrial context to this book.
Included in this book:
Historical aspects of NHCsSynthetic pathways to NHC precursors, free NHCs and complexesMethods of characterisation of NHCs and related complexesElectronic properties of NHCsSteric properties of NHCs and models for their descriptionNHCs for metathesis and cross-coupling reactionsNHCs as organocatalystsNHC Transition-Metal mediated oxidations, additions to multiple bonds, polymerisation and oligomerisation, cyclisations, direct arylations, reactions involving CO, C-F and C-H bond activation, ...Decomposition of NHC-containing catalystsIndustrial applications involving NHC-containing catalysts
N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis provides a fresh view of NHCs since most contributors are young emerging researchers in the field of homogeneous catalysis using NHCs. This group of contributors is complemented by highly
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established academic researchers and an industrialist. This book is comprehensive, from the basic features of NHCs to the latest advances, hence it is suitable for both the novice and the expert.
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This book deals with N-heterocyclic carbenes (NHCs) in Transition Metal Catalysis and Organocatalysis. It includes the following:
- An introduction giving a brief historical aspect on NHCs, the types of NHCs used in catalysis and the acronym of the most common ones - Sections describing their electronic properties (including tables of all data available on the subject), a discussion on the controversial pi-acceptor properties, their steric properties, reactions involving CO with description of systems enabling hydroformylation, as well as carbonylation and decarbonylation reactions - Discussion of the additions to multiple bonds (double and triple), involving the reduction of the bond or not, with particular attention to asymmetric reactions - Presentation of metathesis catalysts, also mentioning the Osmium complexes for these transformations despite their lack of success so far - Sections on oligomerisation and polymerisation reactions, telomerisation, and cyclisation - Overview of reactions involving aryls, with particular care given to more challenging reactions such as C-F bond activation and direct arylations - Description of dehalogenations, followed by an outline of oxidation reactions - A section involving all reactions not mentioned before, allowing room for discussion on reactions less frequently encountered in NHC-based TM-catalysts - A large section to organocatalysis promoted by NHCs
- An introduction giving a brief historical aspect on NHCs, the types of NHCs used in catalysis and the acronym of the most common ones - Sections describing their electronic properties (including tables of all data available on the subject), a discussion on the controversial pi-acceptor properties, their steric properties, reactions involving CO with description of systems enabling hydroformylation, as well as carbonylation and decarbonylation reactions - Discussion of the additions to multiple bonds (double and triple), involving the reduction of the bond or not, with particular attention to asymmetric reactions - Presentation of metathesis catalysts, also mentioning the Osmium complexes for these transformations despite their lack of success so far - Sections on oligomerisation and polymerisation reactions, telomerisation, and cyclisation - Overview of reactions involving aryls, with particular care given to more challenging reactions such as C-F bond activation and direct arylations - Description of dehalogenations, followed by an outline of oxidation reactions - A section involving all reactions not mentioned before, allowing room for discussion on reactions less frequently encountered in NHC-based TM-catalysts - A large section to organocatalysis promoted by NHCs
Inhaltsverzeichnis zu „N-Heterocyclic Carbenes in Transition Metal Catalysis and Organocatalysis “
1. N -Heterocyclic Carbenes - An Introductory Overview.- 2. N -Heterocyclic Carbene Complexes in Additions to Multiple Bonds.- 3. N -Heterocyclic Carbene Complexes in Olefin Metathesis.- 4. N -Heterocyclic Carbene Complexes in Polymerisation, Oligomerisation and Telomerisation Reactions.- 5. N -Heterocyclic Carbene Complexes in Cyclisation Reactions.- 6. N -Heterocyclic Carbene Complexes in Cross-Coupling Reactions.- 7. N -Heterocyclic Carbene Complexes in Arylation Reactions Other than Cross-Couplings.- 8. N -Heterocyclic Carbene Complexes in Dehalogenation Reactions.- 9. N -Heterocyclic Carbene Complexes in Reactions Involving Carbon Monoxide.- 11. N -Heterocyclic Carbene Complexes in Other Transition Metal Mediated Reactions.- 12. N -Heterocyclic Carbenes in Organocatalysis.- 13. N -Heterocyclic Carbene Complexes - Decomposition Pathways.- 14. N -Heterocyclic Carbene Complexes in Industrial Processes.Bibliographische Angaben
- 2010, 340 Seiten, Maße: 16,5 x 24,2 cm, Gebunden, Englisch
- Herausgegeben:Cazin, Catherine S.J.
- Herausgegeben: Catherine S. J. Cazin
- Verlag: Springer Netherlands
- ISBN-10: 904812865X
- ISBN-13: 9789048128655
Sprache:
Englisch
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