Principles of Inorganic Chemistry
(Sprache: Englisch)
Im Gegensatz zu anderen Lehrbüchern, die sich durchgängig auf chemische Anwendungen der Gruppentheorie und der Molekülorbital-Theorie konzentrieren, verfolgt dieses Lehrbuch für Studenten im höheren Grundstudium und zu Beginn des Hauptstudiums bei der...
Leider schon ausverkauft
versandkostenfrei
Buch (Gebunden)
214.60 €
107 DeutschlandCard Punkte
sammeln
- Lastschrift, Kreditkarte, Paypal, Rechnung
- Kostenlose Rücksendung
- Ratenzahlung möglich
Produktdetails
Produktinformationen zu „Principles of Inorganic Chemistry “
Im Gegensatz zu anderen Lehrbüchern, die sich durchgängig auf chemische Anwendungen der Gruppentheorie und der Molekülorbital-Theorie konzentrieren, verfolgt dieses Lehrbuch für Studenten im höheren Grundstudium und zu Beginn des Hauptstudiums bei der Präsentation der anorganischen Chemie einen grundlagenbasierten Ansatz. Von diesem in jeder Hinsicht physikalischen Ansatz profitieren die Studierenden am meisten, wenn es zum Beispiel um die Säure-Base-Theorie im Hinblick auf Molekülorbitale, die Bändertheorie von Feststoffen oder Themen wie die Photochemie geht.
----------------------------------------
Aimed at senior undergraduates and first-year graduate students, this book offers a principles-based approach to inorganic chemistry that, unlike other texts, uses chemical applications of group theory and molecular orbital theory throughout as an underlying framework. This highly physical approach allows students to derive the greatest benefit of topics such as molecular orbital acid-base theory, band theory of solids, and inorganic photochemistry, to name a few.
* Takes a principles-based, group and molecular orbital theory approach to inorganic chemistry
* The first inorganic chemistry textbook to provide a thorough treatment of group theory, a topic usually relegated to only one or two chapters of texts, giving it only a cursory overview
* Covers atomic and molecular term symbols, symmetry coordinates in vibrational spectroscopy using the projection operator method, polyatomic MO theory, band theory, and Tanabe-Sugano diagrams
* Includes a heavy dose of group theory in the primary inorganic textbook, most of the pedagogical benefits of integration and reinforcement of this material in the treatment of other topics, such as frontier MO acid--base theory, band theory of solids, inorganic photochemistry, the Jahn-Teller effect, and Wade's rules are fully realized
* Very physical in nature compare to other textbooks in the field, taking the time to go through mathematical derivations and to compare and contrast different theories of bonding in order to allow for a more rigorous treatment of their application to molecular structure, bonding, and spectroscopy
* Informal and engaging writing style; worked examples throughout the text; unanswered problems in every chapter; contains a generous use of informative, colorful illustrations
----------------------------------------
Aimed at senior undergraduates and first-year graduate students, this book offers a principles-based approach to inorganic chemistry that, unlike other texts, uses chemical applications of group theory and molecular orbital theory throughout as an underlying framework. This highly physical approach allows students to derive the greatest benefit of topics such as molecular orbital acid-base theory, band theory of solids, and inorganic photochemistry, to name a few.
* Takes a principles-based, group and molecular orbital theory approach to inorganic chemistry
* The first inorganic chemistry textbook to provide a thorough treatment of group theory, a topic usually relegated to only one or two chapters of texts, giving it only a cursory overview
* Covers atomic and molecular term symbols, symmetry coordinates in vibrational spectroscopy using the projection operator method, polyatomic MO theory, band theory, and Tanabe-Sugano diagrams
* Includes a heavy dose of group theory in the primary inorganic textbook, most of the pedagogical benefits of integration and reinforcement of this material in the treatment of other topics, such as frontier MO acid--base theory, band theory of solids, inorganic photochemistry, the Jahn-Teller effect, and Wade's rules are fully realized
* Very physical in nature compare to other textbooks in the field, taking the time to go through mathematical derivations and to compare and contrast different theories of bonding in order to allow for a more rigorous treatment of their application to molecular structure, bonding, and spectroscopy
* Informal and engaging writing style; worked examples throughout the text; unanswered problems in every chapter; contains a generous use of informative, colorful illustrations
Klappentext zu „Principles of Inorganic Chemistry “
Aimed at senior undergraduates and first-year graduate students, this book offers a principles-based approach to inorganic chemistry that, unlike other texts, uses chemical applications of group theory and molecular orbital theory throughout as an underlying framework. This highly physical approach allows students to derive the greatest benefit of topics such as molecular orbital acid-base theory, band theory of solids, and inorganic photochemistry, to name a few.* Takes a principles-based, group and molecular orbital theory approach to inorganic chemistry* The first inorganic chemistry textbook to provide a thorough treatment of group theory, a topic usually relegated to only one or two chapters of texts, giving it only a cursory overview* Covers atomic and molecular term symbols, symmetry coordinates in vibrational spectroscopy using the projection operator method, polyatomic MO theory, band theory, and Tanabe-Sugano diagrams* Includes a heavy dose of group theory in the primary inorganic textbook, most of the pedagogical benefits of integration and reinforcement of this material in the treatment of other topics, such as frontier MO acid--base theory, band theory of solids, inorganic photochemistry, the Jahn-Teller effect, and Wade's rules are fully realized* Very physical in nature compare to other textbooks in the field, taking the time to go through mathematical derivations and to compare and contrast different theories of bonding in order to allow for a more rigorous treatment of their application to molecular structure, bonding, and spectroscopy* Informal and engaging writing style; worked examples throughout the text; unanswered problems in every chapter; contains a generous use of informative, colorful illustrations
Inhaltsverzeichnis zu „Principles of Inorganic Chemistry “
Preface xiAcknowledgements xvChapter 1 The Composition of Matter 11.1 Early Descriptions of Matter 11.2 Visualizing Atoms 61.3 The Periodic Table 81.4 The Standard Model 9Exercises 12Bibliography 13Chapter 2 The Structure of the Nucleus 152.1 The Nucleus 152.2 Nuclear Binding Energies 162.3 Nuclear Reactions: Fusion and Fission 172.4 Radioactive Decay and The Band of Stability 222.5 The Shell Model of the Nucleus 272.6 The Origin of the Elements 30Exercises 38Bibliography 39Chapter 3 A Brief Review of Quantum Theory 413.1 TheWavelike Properties of Light 413.2 Problems with the Classical Model of the Atom 483.3 The Bohr Model of The Atom 553.4 Implications of Wave-Particle Duality 583.5 Postulates of Quantum Mechanics 643.6 The Schrödinger Equation 673.7 The Particle in a Box Problem 703.8 The Harmonic Oscillator Problem 75Exercises 78Bibliography 79Chapter 4 Atomic Structure 814.1 The Hydrogen Atom 814.1.1 The Radial Wave Functions 824.1.2 The Angular Wave Functions 864.2 Polyelectronic Atoms 914.3 Electron Spin and the Pauli Principle 934.4 Electron Configurations and the Periodic Table 964.5 Atomic Term Symbols 984.5.1 Extracting Term Symbols Using Russell-Saunders Coupling 1004.5.2 Extracting Term Symbols Using jj Coupling 1024.5.3 Correlation between RS (LS) Coupling and jj Coupling 1044.6 Shielding and Effective Nuclear Charge 105Exercises 107Bibliography 108Chapter 5 Periodic Properties of the Elements 1095.1 The Modern Periodic Table 1095.2 Radius 1115.3 Ionization Energy 1185.4 Electron Affinity 1215.5 The Uniqueness Principle 1225.6 Diagonal Properties 1245.7 The Metal-Nonmetal Line 1255.8 Standard Reduction Potentials 1265.9 The Inert-Pair Effect 1295.10 Relativistic Effects 1305.11 Electronegativity 133Exercises 136Bibliography 137Chapter 6 An Introduction to Chemical Bonding 1396.1 The Bonding in Molecular Hydrogen 1396.2 Lewis Structures 1406.3 Covalent Bond Lengths and Bond Dissociation Energies 1446.4 Resonance 1466.5 Polar Covalent Bonding
... mehr
149Exercises 153Bibliography 154Chapter 7 Molecular Geometry 1557.1 The VSEPR Model 1557.2 The Ligand Close-Packing Model 1707.3 A Comparison of The VSEPR and LCP Models 175Exercises 176Bibliography 177Chapter 8 Molecular Symmetry 1798.1 Symmetry Elements and Symmetry Operations 1798.1.1 Identity, E 1808.1.2 Proper Rotation, Cn 1818.1.3 Reflection, sigma 1828.1.4 Inversion, i 1838.1.5 Improper Rotation, Sn 1838.2 Symmetry Groups 1868.3 Molecular Point Groups 1918.4 Representations 1958.5 Character Tables 2028.6 Direct Products 2098.7 Reducible Representations 214Exercises 222Bibliography 224Chapter 9 Vibrational Spectroscopy 2279.1 Overview of Vibrational Spectroscopy 2279.2 Selection Rules for IR and Raman-Active Vibrational Modes 2319.3 Determining The Symmetries of The Normal Modes of Vibration 2359.4 Generating Symmetry Coordinates Using The Projection Operator Method 2439.5 Resonance Raman Spectroscopy 252Exercises 256Bibliography 258Chapter 10 Covalent Bonding 25910.1 Valence Bond Theory 25910.2 Molecular Orbital Theory: Diatomics 27810.3 Molecular Orbital Theory: Polyatomics 29210.4 Molecular Orbital Theory: pi Orbitals 30510.5 Molecular Orbital Theory: More Complex Examples 31710.6 Borane and Carborane Cluster Compounds 325Exercises 334Bibliography 336Chapter 11 Metallic Bonding 33911.1 Crystalline Lattices 33911.2 X-Ray Diffraction 34511.3 Closest-Packed Structures 35011.4 The Free Electron Model of Metallic Bonding 35511.5 Band Theory of Solids 36011.6 Conductivity in Solids 37411.7 Connections Between Solids and Discrete Molecules 383Exercises 384Bibliography 388Chapter 12 Ionic Bonding 39112.1 Common Types of Ionic Solids 39112.2 Lattice Enthalpies and The Born-Haber Cycle 39812.3 Ionic Radii and Pauling's Rules 40412.4 The Silicates 41712.5 Zeolites 42212.6 Defects in Crystals 423Exercises 426Bibliography 428Chapter 13 Structure and Bonding 43113.1 A Reexamination of Crystalline Solids 43113.2 Intermediate Types of Bonding in Solids 43413.3 Quantum Theory of Atoms in Molecules (QTAIM) 443Exercises 449Bibliography 452Chapter 14 Structure and Reactivity 45314.1 An Overview of Chemical Reactivity 45314.2 Acid-Base Reactions 45514.3 Frontier Molecular Orbital Theory 46714.4 Oxidation-Reduction Reactions 47314.5 A Generalized View of Molecular Reactivity 475Exercises 480Bibliography 481Chapter 15 An Introduction to Coordination Compounds 48315.1 A Historical Overview of Coordination Chemistry 48315.2 Types of Ligands and Nomenclature 48715.3 Stability Constants 49015.4 Coordination Numbers and Geometries 49215.5 Isomerism 49815.6 The Magnetic Properties of Coordination Compounds 501Exercises 506Bibliography 508Chapter 16 Structure, Bonding, and Spectroscopy of Coordination Compounds 50916.1 Valence Bond Model 50916.2 Crystal Field Theory 51216.3 Ligand Field Theory 52516.4 The Angular Overlap Method 53416.5 Molecular Term Symbols 54116.5.1 Scenario 1--All the Orbitals Are Completely Occupied 54616.5.2 Scenario 2--There Is a Single Unpaired Electron in One of the Orbitals 54616.5.3 Scenario 3--There Are Two Unpaired Electrons in Two Different Orbitals 54616.5.4 Scenario 4--A Degenerate Orbital Is Lacking a Single Electron 54716.5.5 Scenario 5--There Are Two Electrons in a Degenerate Orbital 54716.5.6 Scenario 6--There Are Three Electrons in a Triply Degenerate Orbital 54716.6 Tanabe-Sugano Diagrams 54916.7 Electronic Spectroscopy of Coordination Compounds 55416.8 The Jahn-Teller Effect 564Exercises 566Bibliography 570Chapter 17 Reactions of Coordination Compounds 57317.1 Kinetics Overview 57317.2 Octahedral Substitution Reactions 57717.2.1 Associative (A) Mechanism 57817.2.2 Interchange (I) Mechanism 57917.2.3 Dissociative (D) Mechanism 58017.3 Square Planar Substitution Reactions 58517.4 Electron Transfer Reactions 59317.5 Inorganic Photochemistry 60617.5.1 Photochemistry of Chromium(III) Ammine Compounds 60717.5.2 Light-Induced Excited State Spin Trapping in Iron(II) Compounds 61117.5.3 MLCT Photochemistry in Pentaammineruthenium(II) Compounds 61517.5.4 Photochemistry and Photophysics of Ruthenium(II) Polypyridyl Compounds 617Exercises 622Bibliography 624Chapter 18 Structure and Bonding in Organometallic Compounds 62718.1 Introduction to Organometallic Chemistry 62718.2 Electron Counting and the 18-Electron Rule 62818.3 Carbonyl Ligands 63118.4 Nitrosyl Ligands 63518.5 Hydride and Dihydrogen Ligands 63818.6 Phosphine Ligands 64018.7 Ethylene and Related Ligands 64118.8 Cyclopentadiene and Related Ligands 64518.9 Carbenes, Carbynes, and Carbidos 648Exercises 651Bibliography 654Chapter 19 Reactions of Organometallic Compounds 65519.1 Some General Principles 65519.2 Organometallic Reactions Involving Changes at the Metal 65619.2.1 Ligand Substitution Reactions 65619.2.2 Oxidative Addition and Reductive Elimination 65819.3 Organometallic Reactions Involving Changes at the Ligand 66419.3.1 Insertion and Elimination Reactions 66419.3.2 Nucleophilic Attack on the Ligands 66719.3.3 Electrophilic Attack on the Ligands 66919.4 Metathesis Reactions 67019.4.1 pi-Bond Metathesis 67019.4.2 Ziegler-Natta Polymerization of Alkenes 67119.4.3 sigma-Bond Metathesis 67119.5 Commercial Catalytic Processes 67419.5.1 Catalytic Hydrogenation 67419.5.2 Hydroformylation 67419.5.3 Wacker-Smidt Process 67619.5.4 Monsanto Acetic Acid Process 67719.6 Organometallic Photochemistry 67819.6.1 Photosubstitution of CO 67819.6.2 Photoinduced Cleavage of Metal-Metal Bonds 68019.6.3 Photochemistry of Metallocenes 68219.7 The Isolobal Analogy and Metal-Metal Bonding in Organometallic Clusters 683Exercises 689Bibliography 691Appendix: A Derivation of the Classical Wave Equation 693Bibliography 694Appendix: B Character Tables 695Bibliography 708Appendix: C Direct Product Tables 709Bibliography 713Appendix: D Correlation Tables 715Bibliography 721Appendix: E The 230 Space Groups 723Bibliography 728Index 729
... weniger
Autoren-Porträt von Brian W. Pfennig
Brian W. Pfennig , PhD, received his undergraduate B.S. degree in chemistry at Albright College in 1988. He earned his Ph.D. in 1992 in the field of physical inorganic chemistry at Princeton University with Dr. Andrew B. Bocarsly, studying the photochemistry of organometallic sandwich compounds and electron transfer in multinuclear mixed-valence coordination compounds. Dr. Pfennig has held a number of different teaching appointments at small liberal arts colleges, including Franklin & Marshall College, Haverford College, Vassar College, and Ursinus College. During his 20-year teaching career, he has taught general chemistry, an accelerated one-semester general chemistry course, both introductory and advanced inorganic chemistry, bio-inorganic chemistry, and inorganic and organometallic photochemistry, as well as serving as the general chemistry laboratory coordinator at Ursinus College for the past 10 years. He is also actively engaged in research with undergraduates in the areas of inorganic photochemistry, electrochemistry, and electron transfer processes occurring in multinuclear mixed-valence coordination compounds. He has also published several papers in the area of chemical education.Bibliographische Angaben
- Autor: Brian W. Pfennig
- 2015, 760 Seiten, mit Abbildungen, Maße: 22,1 x 28,6 cm, Gebunden, Englisch
- Verlag: Wiley & Sons
- ISBN-10: 1118859103
- ISBN-13: 9781118859100
- Erscheinungsdatum: 20.03.2015
Sprache:
Englisch
Kommentar zu "Principles of Inorganic Chemistry"
0 Gebrauchte Artikel zu „Principles of Inorganic Chemistry“
| Zustand | Preis | Porto | Zahlung | Verkäufer | Rating |
|---|
Schreiben Sie einen Kommentar zu "Principles of Inorganic Chemistry".
Kommentar verfassen