Solid Oxide Fuel Cells
From Electrolyte-Based to Electrolyte-Free Devices
(Sprache: Englisch)
Presents innovative approaches towards affordable, highly efficient, and reliable sustainable energy systems
Written by leading experts on the subject, this book provides not only a basic introduction and understanding of conventional fuel cell...
Written by leading experts on the subject, this book provides not only a basic introduction and understanding of conventional fuel cell...
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Klappentext zu „Solid Oxide Fuel Cells “
Presents innovative approaches towards affordable, highly efficient, and reliable sustainable energy systemsWritten by leading experts on the subject, this book provides not only a basic introduction and understanding of conventional fuel cell principle, but also an updated view of the most recent developments in this field. It focuses on the new energy conversion technologies based on both electrolyte and electrolyte-free fuel cells?from advanced novel ceria-based composite electrolyte low temperature solid oxide fuel cells to non-electrolyte fuel cells as advanced fuel-to-electricity conversion technology.
Solid Oxide Fuel Cells: From Electrolyte-Based to Electrolyte-Free Devices is divided into three parts. Part I covers the latest developments of anode, electrolyte, and cathode materials as well as the SOFC technologies. Part II discusses the non-electrolyte or semiconductor-based membrane fuel cells. Part III focuses on engineering efforts on materials, technology, devices and stack developments, and looks at various applications and new opportunities of SOFC using both the electrolyte and non-electrolyte principles, including integrated fuel cell systems with electrolysis, solar energy, and more.
-Offers knowledge on how to realize highly efficient fuel cells with novel device structures
-Shows the opportunity to transform the future fuel cell markets and the possibility to commercialize fuel cells in an extended range of applications
-Presents a unique collection of contributions on the development of solid oxide fuel cells from electrolyte based to non-electrolyte-based technology
-Provides a more comprehensive understanding of the advances in fuel cells and bridges the knowledge from traditional SOFC to the new concept
-Allows readers to track the development from the conventional SOFC to the non-electrolyte or single-component fuel cell
Solid Oxide Fuel Cells: From Electrolyte-Based to Electrolyte-Free Devices will serve as an important
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reference work to students, scientists, engineers, researchers, and technology developers in the fuel cell field.
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Inhaltsverzeichnis zu „Solid Oxide Fuel Cells “
PREFACE PART I SOLID OXIDE FUEL CELL WITH IONIC CONDUCTING ELECTROLYTE INTRODUCTION An introduction to the principles of fuel cells Materials and technologies New electrolyte developments on LTSOFC Beyond the state-of-the-art - the electrolyte-free fuel cell (EFFC) Beyond the SOFC SOLID-STATE ELECTROLYTES FOR SOFC Introduction Single-phase SOFC Electrolytes Ion Conduction/transportation in electrolytes Composite Electrolytes NANOCOFC and material design principle Concluding remarks Acknowledgments CATHODES FOR SOLID OXIDE FUEL CELL Introduction Overview of Cathode Reaction Mechanism Development of Cathode Materials Microstructure Optimization of Cathode Materials Summary ANODES FOR SOLID OXIDE FUEL CELL Abstract Introduction Overview of Anode Reaction Mechanism Development of Anode Materials Development of kinetics, reaction mechanism and model of the anode Summary and outlook Acknowledgment DESIGN AND DEVELOPMENT OF SOFC STACKS Introduction Change of cell output performance under D interface contact Control design of transition from D to D interface contact and their quantitative contribution differentiation Conclusions References PART II ELECTROLYTE-FREE FUEL CELLS: MATERIALS, TECHNOLOGIES AND WORKING PRINCIPLES ELECTROLYTE-FREE SOFCS: MATERIALS, TECHNOLOGIES AND WORKING PRINCIPLES Concept of the electrolyte-free fuel cell SLFC using the ionic conductor based electrolyte Developments on advanced SLFC From SLFCs to semiconductor-ionic fuel cells (SIFCs) The SLFC working principle Remarks Acknowledgments References CERIA FLUORITE ELECTROLYTES FROM IONIC TO MIXED ELECTRONIC AND IONIC MEMBRANES Introduction Doped ceria as the electrolyte for intermediate temperature SOFCs Surface doping for low temperature SOFCs Non-doped ceria for advanced low temperature SOFCs References CHARGE TRANSFER IN OXIDE SOLID FUEL CELLS Oxygen diffusion in perovskite oxides Proton diffusion in Perovskite-Type Oxides Enhanced ion conductivity in oxide heterostructures Summary
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Acknowledgements References MATERIAL DEVELOPMENT II: NATURAL MATERIAL-BASED COMPOSITES FOR ELECTROLYTE LAYER-FREE FUEL CELLS Introduction Industrial-grade rare-earth for EFFCs Natural hematite for EFFCs Natural CuFe-oxide minerals for EFFCs Bio-derived calcite for EFFC References CHARGE TRANSFER, TRANSPORTATION AND SIMULATION Physical aspects Electrochemical aspects Ionic conduction enhancement in heterostructure composites Charge transportation mechanism and coupling effects Surface and interfacial state induced superionic conduction and transportation Ionic transport number measurements Determination of electron and ionic conductivities in EFFCs EIS analysis Semiconductor band effects on the ionic conduction, device performance Simulations Acknowledgments References ELECTROLYTE-FREE FUEL CELL: PRINCIPLES AND CROSSLINK RESEARCH Introduction Fundamental considerations of fuel cell semiconductor electrochemistry Working principle of semiconductor-based fuel cells and crossing link sciences Extending applications by coupling devices Final Remarks Acknowledgments References PART III FUEL CELLS: FROM TECHNOLOGY TO APPLICATIONS SCALING UP MATERIALS AND TECHNOLOGY FOR SLFC Single layer fuel cell (SLFC) engineering materials Scaling up single layer fuel cell devices- tape casting & hot pressing Scaling up single layer fuel cell devices - thermal spray coating technology Short stack Tests and evaluations Durability testing A case study for the cell degradation mechanism Continuous efforts and future developments Concluding remarks Reference PLANAR SOFC STACK DESIGN AND DEVELOPMENT Internal manifold and external manifold Interface between an interconnect plate and a single cell Anti-oxidation coating of the interconnect plate Design the flow field of interconnect plate and control the temperature distribution The importance of sealing The life of the stack, the chemical problems on the interface Towards market products Concluding remarks Reference ENERGY SYSTEM INTEGRATION AND FUTURE PERSPECTIVES Solar Cell and Fuel Cell Fuel cell-solar cell integration Solar-Electrolysis-Fuel Cell Integration Fuel cell-Biomass integration The Fuel cell system modelling using biogas The fuel cell system efficiency (heating and electrical) Integrated new clean energy system Summary References
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Autoren-Porträt
Bin Zhu, PhD, is Professor in the Department of Energy Technology at the Royal Institute of Technology in Stockholm (KTH), Sweden. He has published more than 250 scientific papers in nano-composite ionic conductors and new semiconductor-ionic materials for advanced fuel cells.Rizwan Raza, PhD, is Assistant Professor in the Department of Physics in COMSATS Institute of Information Technology, Pakistan. He has published more than 100 scientific papers.
Liangdong Fan, PhD, is Lecturer in the College of Chemistry and Environmental Engineering at Shenzhen University, China. His interests focus on novel nanocomposite functional materials for fuel cells and electro-catalysis.
Chunwen Sun is a Professor at Beijing Institute of Nanoenergy and Nanosystems (BINN), Chinese Academy of Sciences (CAS). His research interests include energy storage and conversion, e.g., lithium/sodium-ion batteries, metal-air batteries, all-solid-state batteries, fuel cells and self-power systems.
Bibliographische Angaben
- 2020, 1. Auflage, XIV, 472 Seiten, 259 farbige Abbildungen, 81 Schwarz-Weiß-Abbildungen, Maße: 1,5 x 5,2 cm, Gebunden, Englisch
- Herausgegeben: Bin Zhu, Rizwan Raza, Liangdong Fan, Chunwen Sun
- Verlag: Wiley-VCH
- ISBN-10: 352734411X
- ISBN-13: 9783527344116
- Erscheinungsdatum: 18.04.2020
Sprache:
Englisch
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