Stochastic Processes in Polymeric Fluids
Tools and Examples for Developing Simulation Algorithms
(Sprache: Englisch)
This book consists of two strongly interweaved parts: the mathematical theory of stochastic processes and its applications to molecular theories of polymeric fluids. The comprehensive mathematical background provided in the first part should be equally...
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Klappentext zu „Stochastic Processes in Polymeric Fluids “
This book consists of two strongly interweaved parts: the mathematical theory of stochastic processes and its applications to molecular theories of polymeric fluids. The comprehensive mathematical background provided in the first part should be equally useful in many other branches of engineering and the natural sciences. As a benefit from the second part one gains a more direct understanding of polymer dynamics, one can more easily identify exactly solvable models, and one can develop efficient computer simulation algorithms in a straightforward manner. In view of the examples and applications to problems from the front line of science, this volume may be used as a basic textbook or as a reference book. Program examples written in FORTRAN are available via ftp from ftp.springer.de/pub/chemistry/polysim/.
Inhaltsverzeichnis zu „Stochastic Processes in Polymeric Fluids “
1 Stochastic Processes, Polymer Dynamics, and Fluid Mechanics.- 1.1 Approach to Kinetic Theory Models.- 1.2 Flow Calculation and Material Functions.- 1.2.1 Shear Flows.- 1.2.2 General Extensional Flows.- 1.2.3 The CONNFFESSIT Idea.- References.- I Stochastic Processes.- 2 Basic Concepts from Stochastics.- 2.1 Events and Probabilities.- 2.1.1 Events and ?-Algebras.- 2.1.2 Probability Axioms.- 2.1.3 Gaussian Probability Measures.- 2.2 Random Variables.- 2.2.1 Definitions and Examples.- 2.2.2 Expectations and Moments.- 2.2.3 Joint Distributions and Independence.- 2.2.4 Conditional Expectations and Probabilities.- 2.2.5 Gaussian Random Variables.- 2.2.6 Convergence of Random Variables.- 2.3 Basic Theory of Stochastic Processes.- 2.3.1 Definitions and Distributions.- 2.3.2 Gaussian Processes.- 2.3.3 Markov Processes.- 2.3.4 Martingales.- References.- 3 Stochastic Calculus.- 3.1 Motivation.- 3.1.1 Naive Approach to Stochastic Differential Equations.- 3.1.2 Criticism of the Naive Approach.- 3.2 Stochastic Integration.- 3.2.1 Definition of the Itô Integral.- 3.2.2 Properties of the Itô Integral.- 3.2.3 Itô's Formula.- 3.3 Stochastic Differential Equations.- 3.3.1 Definitions and Basic Theorems.- 3.3.2 Linear Stochastic Differential Equations.- 3.3.3 Fokker-Planck Equations.- 3.3.4 Mean Field Interactions.- 3.3.5 Boundary Conditions.- 3.3.6 Stratonovich's Stochastic Calculus.- 3.4 Numerical Integration Schemes.- 3.4.1 Euler's Method.- 3.4.2 Mil'shtein's Method.- 3.4.3 Weak Approximation Schemes.- 3.4.4 More Sophisticated Methods.- References.- II Polymer Dynamics.- 4 Bead-Spring Models for Dilute Solutions.- 4.1 Rouse Model.- 4.1.1 Analytical Solution for the Equations of Motion.- 4.1.2 Stress Tensor.- 4.1.3 Material Functions in Shear and Extensional Flows.- 4.1.4 A Primer in Brownian Dynamics Simulations.- 4.1.5 Variance Reduced Simulations.- 4.2 Hydrodynamic Interaction.- 4.2.1 Description of Hydrodynamic Interaction.- 4.2.2 Zimm Model.- 4.2.3 Long Chain Limit and
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Universal Behavior.- 4.2.4 Gaussian Approximation.- 4.2.5 Simulation of Dumbbells.- 4.3 Nonlinear Forces.- 4.3.1 Excluded Volume.- 4.3.2 Finite Polymer Extensibility.- References.- 5 Models with Constraints.- 5.1 General Bead-Rod-Spring Models.- 5.1.1 Philosophy of Constraints.- 5.1.2 Formulation of Stochastic Differential Equations.- 5.1.3 Generalized Coordinates Versus Constraint Conditions.- 5.1.4 Numerical Integration Schemes.- 5.1.5 Stress Tensor.- 5.2 Rigid Rod Models.- 5.2.1 Dilute Solutions of Rod-like Molecules.- 5.2.2 Liquid Crystal Polymers.- References.- 6 Reptation Models for Concentrated Solutions and Melts.- 6.1 Doi-Edwards and Curtiss-Bird Models.- 6.1.1 Polymer Dynamics.- 6.1.2 Stress Tensor.- 6.1.3 Simulations in Steady Shear Flow.- 6.1.4 Efficiency of Simulations.- 6.2 Reptating-Rope Model.- 6.2.1 Basic Model Equations.- 6.2.2 Results for Steady Shear Flow.- 6.3 Modified Reptation Models.- 6.3.1 A Model Related to "Double Reptation".- 6.3.2 Doi-Edwards ModelWithout Independent Alignment.- References.- Landmark Papers and Books.- Solutions to Exercises.- References.- Author Index.
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Bibliographische Angaben
- Autor: Hans C. Öttinger
- 1996, 362 Seiten, Maße: 23,5 cm, Kartoniert (TB), Englisch
- Verlag: Springer
- ISBN-10: 354058353X
- ISBN-13: 9783540583530
Sprache:
Englisch
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