The Mizoroki-Heck Reaction
(Sprache: Englisch)
Exploring the importance of Richard F. Heck s carbon coupling reaction, this book highlights the subject of the 2010 Nobel Prize in Chemistry for palladium catalyzed cross couplings in organic synthesis, and includes a foreword from Nobel Prize winner Richard F. Heck.
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Exploring the importance of Richard F. Heck s carbon coupling reaction, this book highlights the subject of the 2010 Nobel Prize in Chemistry for palladium catalyzed cross couplings in organic synthesis, and includes a foreword from Nobel Prize winner Richard F. Heck.
Klappentext zu „The Mizoroki-Heck Reaction “
The Mizoroki-Heck reaction is a palladium-catalyzed carbon-carbon bond forming process which is widely used in organic and organometallic synthesis. It has seen increasing use in the past decade as chemists look for strategies enabling the controlled construction of complex carbon skeletons. The Mizoroki-Heck Reaction is the first dedicated volume on this important reaction, including topics on:* mechanisms of the Mizoroki-Heck reaction
* intermolecular Mizoroki-Heck reactions
* focus on regioselectivity and product outcome in organic synthesis
* waste-minimized Mizoroki-Heck reactions
* intramolecular Mizoroki-Heck reactions
* formation of heterocycles
* chelation-controlled Mizoroki-Heck reactions
* the Mizoroki-Heck reaction in domino processes
* oxidative heck-type reactions (Fujiwara-Moritani reactions)
* Mizoroki-Heck reactions with metals other than palladium
* ligand design for intermolecular asymmetric Mizoroki-Heck reactions
* intramolecular enantioselective Mizoroki-Heck reactions
* desymmetrizing Mizoroki-Heck reactions
* applications in combinatorial and solid phase syntheses, and the development of modern solvent systems and reaction techniques
* the asymmetric intramolecular Mizoroki-Heck reaction in natural product total synthesis
Several chapters are devoted to asymmetric Heck reactions with particular focus on the construction of otherwise difficult-to-obtain sterically congested tertiary and quaternary carbons. Industrial and academic applications are highlighted in the final section. The Mizoroki-Heck Reaction will find a place on the bookshelves of any organic or organometallic chemist.
Inhaltsverzeichnis zu „The Mizoroki-Heck Reaction “
I. THE MIZOROKI-HECK REACTION - PROF. DR. ANNY JUTAND1. Mechanisms of the Mizoroki-Heck Reaction
2. Intermolecular Mizoroki-Heck Reactions ( Irina P. Beletskaya and Andrei V. Cheprakov)
3. Intramolecular Mizoroki-Heck Reactions (Axel. B. Machotta and Martin Oestreich)
4. Chelation-Controlled Mizoroki-Heck Reactions (Kenichiro Itami and Jun-ichi Yoshida)
5. The Mizoroki-Heck Reaction in Domino Processes (Lutz F. Tietze and
6. Oxidative Heck-type Reactions (Fujiwara-Moritani Reactions) (Eric M. Ferreira, Haiming Zhang, and Brian M. Stoltz)
7. Mizoroki-Heck Reactions with Metals other than Palladium (Robert Born and Lutz Ackermann)
II. THE ASYMMETRIC MIZOROKI-HECK REACTION
8. Ligand Design for Intermolecular Asymmetric Mizoroki-Heck Reactions (Anthony G. Coyne, Martin O. Fitzpatrick, and Patrick Guiry)
9. Intramolecular Enantioselective Mizoroki-Heck Reactions (James T. Link and Carol K. Wada)
10. Desymmetrizing Mizoroki-Heck Reactions (Masakatsu Shibasaki and Takashi Ohshima)
III. APPLICATIONS OF THE MIZOROKI-HECK REACTION
11. Combinatorial and Solid Phase Syntheses ( Thierry Muller and Stefan Bräse)
12. Modern Solvent Systems and Reaction Techniques (Werner Bonrath, Ulla Létinois, Thomas Netscher, and Jan Schütz)
13. The Asymmetric Intramolecular Mizoroki-Heck Reaction in Natural Product Total Synthesis (Amy B. Dounay and Larry E.)
Index
Autoren-Porträt
Martin Oestreich (born in 1971 in Pforzheim/Germany) is currently Professor of Organic Chemistry at the Technische Universität Berlin. He received his diploma degree with Paul Knochel (Marburg, 1996) and his doctoral degree with Dieter Hoppe (Münster, 1999). After a two year postdoctoral stint with Larry E. Overman (Irvine, 1999 2001), he completed his habilitation with Reinhard Brückner (Freiburg, 2001 2005) and was appointed as Professor of Organic Chemistry at the Westfälische Wilhelms Universität Münster (2006 2011). He also held visiting positions at Cardiff University in Wales (2005) and at The Australian National University in Canberra (2010).
Bibliographische Angaben
- 2009, 1. Auflage, 568 Seiten, Maße: 17,2 x 24,7 cm, Gebunden, Englisch
- Herausgegeben: Martin Oestreich
- Verlag: Wiley & Sons
- ISBN-10: 0470033940
- ISBN-13: 9780470033944
- Erscheinungsdatum: 02.03.2009
Sprache:
Englisch
Pressezitat
"It is by far the most authoritative book in this area written to date and has employed many of the major contributors in the area over recent years to provide chapters, resulting in good...coverage of the literature." ( Applied Organimetallic Chemistry , March 2010) "I am convinced that this book will rapidly become the most important reference text for research chemists in academia and industry who seek orientation in the rapidly growing and – for the layman – confusing field described as the "'Mizoroki–Heck reaction'." ( Synthesis , March 2010) "This book is a welcome addition to the subject and provides almost all the areas you would want to be covered." ( Organic Process Research & Development Journal , 2010) "The selection and clear arrangement of the competently written chapters of this book is well done, giving a rapid general overview of current knowledge about various aspects of this important reaction." ( Angewandte Chemie December 2009)
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