Catalysis without Precious Metals (ePub)

Preface CATALYSIS INVOLVING THE H*TRANSFER REACTIONS OF FIRST-ROW TRANSITION METALS H*Transfer Between M-H Bonds and Organic Radicals H*Transfer Between Ligands and Organic Radicals H*Transfer Between M-H and C-C Bonds Chain Transfer Catalysis Catalysis of Radical Cyclizations Competing Methods for the Cyclization of Dienes Summary and Conclusions CATALYYTIC REDUCTION OF DINITROGEN TO AMMONIA BY MOLYBDENUM Introduction Some Characteristics of Triamidoamine Complexes Possible [HIPTN3N]Mo Intermediates in a Catalytic Reduction of Molecular Nitrogen Interconversion of Mo(NH3) and Mo(N2) Catalytic Reduction of Dinitrogen MoH and Mo(H2) Ligand and Metal Variations Comments MOLYBDENUM AND TUNGSTEN CATALYSTS FOR HYDROGENATION, HYDROSILYLATION AND HYDROLYSIS Introduction Proton Transfer Reactions of Metal Hydrides Hydride Transfer Reactdions of Metal Hydrides Stoichiometric Hydride Transfer Reactivity of Anionic Metal Hydride Complexes Catalytic Hydrogenation of Ketones with Anionic Metal Hydrides Ionic Hydrogenation of Ketones Using Metal Hydrides and Added Acid Ionic Hydrogenations from Dihydrides: Delivery of the Proton and Hydride from One Metal Catalytic Ionic Hydrogenations With Mo and W Catalysts Mo Phosphine Catalysts With Improved Lifetimes Tungsten Hydrogenation Catalysts with N-Heterocyclic Carbene Ligands Catalysts for Hydrosilylation of Ketones Cp2Mo Catalysts for Hydrolysis, Hydrogenations and Hydrations Conclusion MODERN ALCHEMY: REPLACING PRECIOUS METALS WITH IRON IN CATALYTIC ALKENE AND CARBONYL HYDROGENATION REACTIONS Introduction Alkene Hydrogenation Carbonyl Hydrogenation Outlook OLEFIN OOLIGOMERIZATIONS AND POLYMERIZATIONS CATALYZED BY IRON AND COBALT COMPLEXES BEARING BIS(IMINO)PYRIDINE LIGANDS Introduction Precatalyst Synthesis Precatalyst Activation and Catalysis The Active Catalyst and Mechanism Other Applications Conclusions and Outlook COBALT AND NICKEL CATALYZED REACTIONS INVOLVING C-H AND C-N ACTIVATION REACTIONS Introduction Catalysis with

After 21 years at Brookhaven National Laboratory in Long Island, New York, Morris Bullock moved to Pacific Northwest National Laboratory in 2006, where he is a Laboratory Fellow, as well as Director of the Center for Molecular Electrocatalysis. Dr. Bullock's research interests focus on reactivity of metal hydrides, including proton transfer, hydride transfer, and hydrogen atom transfer reactions, and on the development of molecular catalysts for the oxidation of hydrogen and production of hydrogen.

Dieses eBook können Sie uneingeschränkt auf allen Geräten der tolino Familie lesen. Zum Lesen auf sonstigen eReadern und am PC benötigen Sie eine Adobe ID.