Total Synthesis of (±)-Maoecrystal V / Springer Theses (PDF)
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In this thesis, the author describes the total synthesis of natural product Maoecrystal V in detail. In the first part of the thesis, the author introduces the research background and reviews the research progress in total synthesis of Maoecrystal V. In the second part, the author develops a novel and concise approach for the stereoselective construction of the tetracyclic model system of Maoecrystal V. The model system is accomplished in 8 steps with 20% yield. In the third part, the author describes the first successful total synthesis of Maoecrystal V and investigates four strategies for constructing the key tetrahydrofuran oxa-bridge skeleton. The total synthesis starts from a known compound and is accomplished in 17 steps with 1.2% yield. The successful total synthesis of Maoecrystal V will contribute to the development of efficient synthetic strategies for natural products and other compounds with complex structures.
- Autor: Jianxian Gong
- 2014, 2014, 137 Seiten, Englisch
- Verlag: Springer-Verlag GmbH
- ISBN-10: 3642543049
- ISBN-13: 9783642543043
- Erscheinungsdatum: 08.07.2014
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- Größe: 10 MB
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