Produktinformationen zu „Isoconversional Kinetics of Thermally Stimulated Processes “
Klappentext zu „Isoconversional Kinetics of Thermally Stimulated Processes “
The use of isoconversional kinetic methods for analysis of thermogravimetric and calorimetric data on thermally stimulated processes is quickly growing in popularity. The purpose of this book is to create the first comprehensive resource on the theory and applications of isoconversional methodology. The book introduces the reader to the kinetics of physical and chemical condensed phase processes that occur as a result of changing temperature and discusses how isoconversional analysis can provide important kinetic insights into them. The book will help the readers to develop a better understanding of the methodology, and promote its efficient usage and successful development.
Inhaltsverzeichnis zu „Isoconversional Kinetics of Thermally Stimulated Processes “
1. Some basics en route to isoconversional methodology1.1. From condensed phase kinetics to isoconversional principle1.2. Understanding variable activation energy1.3. Obtaining computation worthy data2. Isoconversional methodology2.1. Evolution of isoconversional methods2.1.1. Early methods2.1.2. Modern methods2.2. Estimating reaction models and preexponential factors2.2.1. Prelude2.2.2. The use of the compensation effect2.2.3. The use of the y(¿) or z(¿) master plots2.3. Kinetic predictions2.3.1. Why predictions?2.3.2. Model-based vs. model-free2.3.3. Understanding precision and accuracy of predictions 3. Physical Processes3.1. Phases and transitions between them3.2. Vaporization and Sublimation3.2.1. Background3.2.2. Isoconversional treatment3.3. Glass transition3.3.1. Background3.3.2. Isoconversional treatment3.4. Glass aging3.4.1. Background3.4.2. Isoconversional treatment3.4.3. Activation energies of ¿-relaxation from DSC3.5. Nucleation3.6. Crystallization of polymers3.6.1. Background3.6.2. Isoconversional treatment3.7. Melting of polymers3.7.1. Background3.7.2. Isoconversional treatment3.8. Solid-solid transitions3.8.1. Background3.8.2. Isoconversional treatment3.9. Mixing and demixing3.9.1. Background3.9.2. Isoconversional treatment3.10. Gelation and gel melting3.10.1. Background3.10.2. Isoconversional treatment of gelation3.10.3. Isoconversional treatment of gel melting3.11. Helix-Coil Transition3.11.1. Background3.11.2. Isoconversional treatment of protein denaturation4. Chemical processes4.1. Introduction4.2. Polymerization and Crosslinking4.2.1. Background to polymerization4.2.2. Isoconversional treatment of polymerization4.2.3. Background to crosslinking4.2.4. Isoconversional treatment of crosslinking4.3. Thermal and Thermo-oxidative degradation of polymers4.3.1. Background 4.3.2. Isoconversional treatment 4.4. Thermal decomposition of solids4.4.1. Background 4.4.2. Isoconversional treatment 5. Epilogue
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1. Some basics en route to isoconversional methodology1.1. From condensed phase kinetics to isoconversional principle1.2. Understanding variable activation energy1.3. Obtaining computation worthy data2. Isoconversional methodology2.1. Evolution of isoconversional methods2.1.1. Early methods2.1.2. Modern methods2.2. Estimating reaction models and preexponential factors2.2.1. Prelude2.2.2. The use of the compensation effect2.2.3. The use of the y(¿) or z(¿) master plots2.3. Kinetic predictions2.3.1. Why predictions?2.3.2. Model-based vs. model-free2.3.3. Understanding precision and accuracy of predictions 3. Physical Processes3.1. Phases and transitions between them3.2. Vaporization and Sublimation3.2.1. Background3.2.2. Isoconversional treatment3.3. Glass transition3.3.1. Background3.3.2. Isoconversional treatment3.4. Glass aging3.4.1. Background3.4.2. Isoconversional treatment3.4.3. Activation energies of ¿-relaxation from DSC3.5. Nucleation3.6. Crystallization of polymers3.6.1. Background3.6.2. Isoconversional treatment3.7. Melting of polymers3.7.1. Background3.7.2. Isoconversional treatment3.8. Solid-solid transitions3.8.1. Background3.8.2. Isoconversional treatment3.9. Mixing and demixing3.9.1. Background3.9.2. Isoconversional treatment3.10. Gelation and gel melting3.10.1. Background3.10.2. Isoconversional treatment of gelation3.10.3. Isoconversional treatment of gel melting3.11. Helix-Coil Transition3.11.1. Background3.11.2. Isoconversional treatment of protein denaturation4. Chemical processes4.1. Introduction4.2. Polymerization and Crosslinking4.2.1. Background to polymerization4.2.2. Isoconversional treatment of polymerization4.2.3. Background to crosslinking4.2.4. Isoconversional treatment of crosslinking4.3. Thermal and Thermo-oxidative degradation of polymers4.3.1. Background 4.3.2. Isoconversional treatment 4.4. Thermal decomposition of solids4.4.1. Background 4.4.2. Isoconversional treatment 5. Epilogue
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Autoren-Porträt von Sergey Vyazovkin
Professor Sergey Vyazovkin received his Ph.D. from the Byelorussian State University in 1989. He then joined the Institute for Physical Chemistry (Minsk) where he worked until 1993. Since 1993 he had held visiting positions at the Technical University of Vienna, the University of Toledo, and the University of Nice Sophia-Antipolis. Before joining the University of Alabama at Birmingham, he worked in the University of Utah as a research faculty and the deputy director of the Center for Thermal Analysis. His research interests are concerned with the application of thermal analysis methods to thermally stimulated processes in a wide variety of condensed phase systems. He is a winner of Mettler-Toledo Award in thermal analysis and of James J. Christensen Award in calorimetry. Prof. Vyazovkin is editor of Thermochimica Acta and a member of the editorial board of Macromolecular Rapid Communications and Macromolecular Chemistry and Physics. He is a member of the American Chemical Society Analytical Division, the North American Thermal Analysis Society, and the International Confederation for Thermal Analysis and Calorimetry.
Bibliographische Angaben
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Autor:
Sergey Vyazovkin
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2015, 256 Seiten, Maße: 16 x 24,1 cm, Gebunden, Englisch
- Verlag: Springer International Publishing
- ISBN-10: 3319141740
- ISBN-13: 9783319141749
- Erscheinungsdatum: 30.03.2015
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